Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Chapter 14, Problem 61E
Propionic acid,
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How many signals would you expect to see in the
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'C NMR spectrum for the following compound?
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
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Chapter 14 Solutions
Chemistry Atoms First2e
Ch. 14 - Write equations that show NH3 as both a conjugate...Ch. 14 - Write equations that show H2PO4- acting both as an...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - What is the conjugate acid of each of the...Ch. 14 - What is the conjugate acid of each of the...Ch. 14 - Identify and label the Bronsted-Lowry acid, its...Ch. 14 - Identify and label the Bronsted-Lowry acid, its...
Ch. 14 - What are amphiprotic species? Illustrate with...Ch. 14 - State which of the following species are...Ch. 14 - State which of the following species are...Ch. 14 - Is the self-ionization of water endothermic or...Ch. 14 - Explain why a sample of pure water at 40 C is...Ch. 14 - The ionization constant for water (Kw) is 2.91014...Ch. 14 - The ionization constant for water (Kw) is...Ch. 14 - Calculate the pH and the pOH of each of the...Ch. 14 - Calculate the pH and the pOH of each of the...Ch. 14 - What are the pH and pOH of a solution of 2.0 M...Ch. 14 - What are the hydronium and hydroxide ion...Ch. 14 - Calculate the hydrogen ion concentration and the...Ch. 14 - Calculate the hydronium ion concentration and the...Ch. 14 - The hydronium ion concentration in a sample of...Ch. 14 - The hydroxide ion concentration in household...Ch. 14 - Explain why the neutralization reaction of a...Ch. 14 - Explain why the neutralization reaction of a weak...Ch. 14 - Use this list of important industrial compounds...Ch. 14 - The odor of vinegar is due to the presence of...Ch. 14 - Household ammonia is a solution of the weak base...Ch. 14 - Explain why the ionization constant, Ka, for H2SO4...Ch. 14 - Explain why the ionization constant, Ka, for HI is...Ch. 14 - Gastric juice, the digestive ?uid produced in the...Ch. 14 - Nitric acid reacts with insoluble copper (II)...Ch. 14 - What is the ionization constant at 25 C for the...Ch. 14 - What is the ionization constant at 25 C for the...Ch. 14 - Which base, CH3NH2 or (CH3)2NH, is the stronger...Ch. 14 - Which is the stronger acid, NH4+ or HBrO?Ch. 14 - Which is the stronger base, (CH3)3N or H2BO3-?Ch. 14 - Predict which acid in each of the following pairs...Ch. 14 - Predict which compound in each of the following...Ch. 14 - Rank the compounds in each of the following groups...Ch. 14 - Rank the compounds in each of the following groups...Ch. 14 - Both HF and HCN ionize in water to a limited...Ch. 14 - The active ingredient formed by aspirin in the...Ch. 14 - Are the concentrations of hydronium ion and...Ch. 14 - What two common assumptions can simplify...Ch. 14 - Which of the following will increase the percent...Ch. 14 - Which of the following will increase the percent...Ch. 14 - What is the effect on the concentrations of...Ch. 14 - What is the effect on the concentration of...Ch. 14 - Why is the hydronium ion concentration in a...Ch. 14 - From the equilibrium concentrations given,...Ch. 14 - From the equilibrium concentrations given,...Ch. 14 - Determine Kb for the nitrite ion, NO2-. In a...Ch. 14 - Determine Ka for hydrogen sulfate ion, HSO4-. In a...Ch. 14 - Calculate the ionization constant for each of the...Ch. 14 - Calculate the ionization constant for each of the...Ch. 14 - Using the Ka value of 1.4105,placeAl(H2O)63+ in...Ch. 14 - Calculate the concentration of all solute species...Ch. 14 - Propionic acid, C2H5CO2H(Ka=1.341O-5), is used in...Ch. 14 - White vinegar is a 5.0% by mass solution of acetic...Ch. 14 - The ionization constant of lactic acid,...Ch. 14 - Nicotine, C10H14N2 , is a base that will accept...Ch. 14 - The pH of a 0.20-M solution of HP is 1.92....Ch. 14 - The pH of a 0.15-M solution of HSO4- is 1.43....Ch. 14 - The pH of a 0.10-M solution of caffeine is 11.70....Ch. 14 - Tile pH of a solution of household ammonia, a...Ch. 14 - Determine whether aqueous solutions of the...Ch. 14 - Determine whether aqueous solutions of the...Ch. 14 - Novocaine, C13H21O2N2Cl, is the salt of the base...Ch. 14 - Which of the following concentrations would be...Ch. 14 - Calculate the concentration of each species...Ch. 14 - Calculate the concentration of each species...Ch. 14 - Salicylic acid, HOC6H4CO2H , and its derivatives...Ch. 14 - The ion HTe- is an amphiprotic species; it can act...Ch. 14 - Explain why a buffer can be prepared from a...Ch. 14 - Explain why the pH does not change significantly...Ch. 14 - Explain why the pH does not change significantly...Ch. 14 - What is [H3O+] in a solution of 0.25 M CH3CO2H and...Ch. 14 - What is [H3O+] in a solution of 0.075 M HNO2 and...Ch. 14 - What is [OH-] in a solution of 0.125 M CH3NH2 and...Ch. 14 - What is [OH-] in a solution of 1.25 M NH3 and 0.78...Ch. 14 - What is the effect on the concentration of acetic...Ch. 14 - What is the effect on the concentration of...Ch. 14 - What will be the pH of a buffer solution prepared...Ch. 14 - Calculate the pH of a buffer solution prepared...Ch. 14 - How much solid NaCH3CO23H2O must be added to 0300...Ch. 14 - What mass of NH4Cl must be added to 0.750 L of a...Ch. 14 - A buffer solution is prepared from equal volumes...Ch. 14 - A 5.36-g sample of NH4Cl was added to 25.0 mL of...Ch. 14 - Explain how to choose the appropriate acid-base...Ch. 14 - Explain why an acid-base indicator changes color...Ch. 14 - Calculate the pH at the following points in a...Ch. 14 - The indicator dinitrophenol is an acid with a Ka...
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- 1 How many signals do you expect in the 'H NMR spectrum for this molecule? CI CI Cl Write the answer in the table below. Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum. 1 Number of signals in the 'H NMR spectrum. ☐ For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional H atoms to highlight in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at…arrow_forwardwrtie the balanced equation and find the E° when the following half- reactions are combined Zn2+(aq) + 2e---> Zn(s) E°= -0.763V Ag+(aq) + e---> Ag (s) E°=+0.799Varrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forward
- Study this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forwardhow many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forwardcalculate the number of moles of H2 produced from 0.78 moles of Ga and 1.92 moles HCL? 2Ga+6HCL->2GaCl3+3H2arrow_forward
- an adult human breathes 0.50L of air at 1 atm with each breath. If a 50L air tank at 200 atm is available, how man y breaths will the tank providearrow_forwardWhat are the advantages and/or disadvantages of using the MOHR titration method & AOEC method?arrow_forwardAre there any alternative methods better than the MOHR titration to quantitatively determine salt in a sample?arrow_forward
- hybridization of nitrogen of complex moleculesarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1arrow_forwardWhy do we analyse salt?arrow_forward
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