ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Chapter 14, Problem 5LGP
Interpretation Introduction

Interpretation:

The structures of the nicotinamide ring in NADH and NAD+ are to be drawn and the way in which the hydrogen transfer occurs in the conversion of NADH to NAD+ is to be explained.

Concept introduction:

Nicotinamide exists in the oxidized form in NADH and gets converted into an aromatic pyridinium ring on reduction, leading to the formation of NAD+.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

Chapter 14 Solutions

ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT

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