Radioactive decay must be explained as a disintegration reaction which follows first order reaction kinetics. Concept introduction: Rate of radioactive disintegration depends on the number of atoms present at a particular time. It is a first order reaction. Half life i.e t 1 / 2 is independent of initial concentration.

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Last Name, Firs Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $ 4th total 21 total 4H total ZH 2H Statistical H < 3°C-H werkst - product bund abstraction here leads to the mo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Proclict 6 Number of Unique Mono-Chlorinated Products f Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary 'H H-Cl Waterfox

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Question

Chapter 14, Problem 4CO

Interpretation Introduction

Interpretation:

Radioactive decay must be explained as a disintegration reaction which follows first order reaction kinetics.

Concept introduction:

Rate of radioactive disintegration depends on the number of atoms present at a particular time.

It is a first order reaction.

Half life i.e t1/2
is independent of initial concentration.

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Last Name, Firs Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $ 4th total 21 total 4H total ZH 2H Statistical H < 3°C-H werkst - product bund abstraction here leads to the mo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Proclict 6 Number of Unique Mono-Chlorinated Products f Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary 'H H-Cl Waterfox

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