INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
6th Edition
ISBN: 9780134845609
Author: Tro
Publisher: PEARSON
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Chapter 14, Problem 3SAQ
What is the conjugate base of the acid
?
a.
b.
c.
d.
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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OA
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 14 Solutions
INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
Ch. 14 - Which substance is most likely to have a bitter...Ch. 14 - Identity the Brnsted-Lowry base in the reaction....Ch. 14 - What is the conjugate base of the acid HClO4 ? a....Ch. 14 - Prob. 4SAQCh. 14 - Q5. What are the products of the reaction between...Ch. 14 - A 25.00-mL sample of an HNO3 solution is titrated...Ch. 14 - In which solution is [H3O+] less than 0.100 M? a....Ch. 14 - Prob. 8SAQCh. 14 - Prob. 9SAQCh. 14 - What is the pH of a solution with [H3O+]=2.8105M ?...
Ch. 14 - What is [OH] in a solution with a pH of 9.55 ? a....Ch. 14 - A buffer contains HCHO2(aq) and KCHO2(aq). Which...Ch. 14 - 1. What makes tart gummy candies, such as Sour...Ch. 14 - What are the properties of acids? List some foods...Ch. 14 - 3. What is the main component of stomach acid? Why...Ch. 14 - Prob. 4ECh. 14 - What are the properties of bases? Provide some...Ch. 14 - Prob. 6ECh. 14 - Restate the Arrhenius definition of an acid and...Ch. 14 - Prob. 8ECh. 14 - 9. Restate the Brønsted-Lowry definitions of acids...Ch. 14 - Prob. 10ECh. 14 - What is an acidbase neutralization reaction?...Ch. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - 14. Name a metal that a base can dissolve and...Ch. 14 - What is titration? What is the equivalence point?Ch. 14 - Prob. 16ECh. 14 - What is the difference between a strong acid and a...Ch. 14 - Prob. 18ECh. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Does pure water contain any H3O+ ions? Explain...Ch. 14 - Prob. 22ECh. 14 - 23. Give a possible value of and in a solution...Ch. 14 - 24. How is pH defined? A change of 1.0 pH unit...Ch. 14 - 25. How is pOH defined? A change of 2.0 pOH units...Ch. 14 - Prob. 26ECh. 14 - What is a buffer?Ch. 14 - Prob. 28ECh. 14 - Identify each substance as an acid or a base and...Ch. 14 - 30. Identify each substance as an acid or a base...Ch. 14 - 31. For each reaction, identify the Brønsted-Lowry...Ch. 14 - For each reaction, identify the Brnsted-Lowry...Ch. 14 - Determine whether each pair is a conjugate...Ch. 14 - Determine whether each pair is a conjugate...Ch. 14 - Write the formula for the conjugate base of each...Ch. 14 - Prob. 36ECh. 14 - 37. Write the formula for the conjugate acid of...Ch. 14 - Prob. 38ECh. 14 - Write a neutralization reaction for each acid and...Ch. 14 - Write a neutralization reaction for each acid and...Ch. 14 - 41. Write a balanced chemical equation showing how...Ch. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - Prob. 44ECh. 14 - Prob. 45ECh. 14 - Prob. 46ECh. 14 - 47. Four solutions of unknown HCl concentration...Ch. 14 - 48. Four solutions of unknown NaOH concentration...Ch. 14 - 49. A 25.00-mL sample of an solution of unknown...Ch. 14 - 50. A 5.00-mL sample of an solution of unknown...Ch. 14 - What volume in milliliters of a 0.121 M sodium...Ch. 14 - 52. What volume in milliliters of a 0.0985 M...Ch. 14 - Prob. 53ECh. 14 - 54. Classify each acid as strong or...Ch. 14 - Prob. 55ECh. 14 - Determine [H3O+] in each acid solution. If the...Ch. 14 - Prob. 57ECh. 14 - Prob. 58ECh. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - 61. Determine if each solution is acidic, basic,...Ch. 14 - Prob. 62ECh. 14 - Calculate [OH] given [H3O+] in each aqueous...Ch. 14 - Calculate [OH] given [H3O+] in each aqueous...Ch. 14 - Calculate [H3O+] given [OH] in each aqueous...Ch. 14 - 66. Calculate given in each aqueous solution and...Ch. 14 - 67. Classify each solution as acidic, basic, or...Ch. 14 - Prob. 68ECh. 14 - 69. Calculate the pH of each...Ch. 14 - Calculate the pH of each solution. a....Ch. 14 - 71. Calculate of each solution.
a.
b.
c.
d.
Ch. 14 - 72. Calculate of each solution.
a.
b.
c.
d.
Ch. 14 - Prob. 73ECh. 14 - Prob. 74ECh. 14 - 75. Calculate of each solution.
a.
b.
c.
d.
Ch. 14 - 76. Calculate of each solution.
a.
b.
c.
d.
Ch. 14 - Calculate the pH of each solution: a. 0.0155MHBr...Ch. 14 - Prob. 78ECh. 14 - Determine the pOH of each solution and classify it...Ch. 14 - Determine the pOH of each solution and classify it...Ch. 14 - Determine the pOH of each solution. a....Ch. 14 - Prob. 82ECh. 14 - Prob. 83ECh. 14 - Prob. 84ECh. 14 - 85. Determine whether or not each mixture is a...Ch. 14 - Determine whether or not each mixture is a buffer....Ch. 14 - Prob. 87ECh. 14 - 88. Write reactions showing how each of the...Ch. 14 - Prob. 89ECh. 14 - Which substance could you add to each solution to...Ch. 14 - 91. How much 0.100 M HCl is required to completely...Ch. 14 - How much 0.200 M KOH is required to completely...Ch. 14 - What is the minimum volume of 5.0 M HCl required...Ch. 14 - What is the minimum volume of 3.0 M HBr required...Ch. 14 - Prob. 95ECh. 14 - Prob. 96ECh. 14 - A 0.125-g sample of a monoprotic acid of unknown...Ch. 14 - Prob. 98ECh. 14 - 99. People take antacids, such as milk of...Ch. 14 - An antacid tablet requires 25.82 mL of 200 M HCl...Ch. 14 - Prob. 101ECh. 14 - Prob. 102ECh. 14 - Complete the table. (The first row is completed...Ch. 14 - Prob. 104ECh. 14 - Prob. 105ECh. 14 - Prob. 106ECh. 14 - 107. For each strong base solution, determine , ...Ch. 14 - Prob. 108ECh. 14 - 109. As described in Section 14.1, jailed spies on...Ch. 14 - Prob. 110ECh. 14 - 111. What is the pH of a solution formed by mixing...Ch. 14 - Prob. 112ECh. 14 - 113. How many (or ) ions are present in one drop...Ch. 14 - Prob. 114ECh. 14 - Prob. 115ECh. 14 - Prob. 116ECh. 14 - Prob. 117ECh. 14 - Prob. 118ECh. 14 - Prob. 119ECh. 14 - Choose an example of a reaction featuring a...Ch. 14 - 121. Divide your group in two. Have each half of...Ch. 14 - Prob. 122QGWCh. 14 - With group members acting as atoms or ions, act...Ch. 14 - Data Interpretation and Analysis
124. The progress...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
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