Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card
Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card
7th Edition
ISBN: 9781337812269
Author: Nivaldo J. Tro
Publisher: Cengage Learning
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Chapter 14, Problem 39E
Interpretation Introduction

Interpretation:

The rusted piece of iron is to be identified and the reason is to be explained.

Concept Introduction:

Oxidation is the addition of an electronegative element or the removal of an electropositive element in a chemical reaction.

Reduction is the addition of an electropositive element or the removal of an electronegative element in a chemical reaction.

A chemical reaction in which oxidation process and reduction process take place simultaneously is called a redox reaction.

An oxidizing agent is a substance that has the capacity to oxidize the other substances and get reduced in a chemical reaction.

A reducing agent is a substance that has the capacity to reduce the other substances and get oxidized in a chemical reaction.

Non-metals are a better oxidizing agent than metals. They have the capacity to gain electrons and form negative ions. They have the capacity to oxidize the other substances and get reduced.

Metals are a better reducing agent. They have a tendency to lose electrons and form positive ions. They have the capacity to reduce the other substances and get oxidized.

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2. Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction energies in order to identify the lower energy conformer for each stereoisomer. Based on your calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable. [1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3 CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol) all-cis-1,2,3- 1 all-cis-1,2,4- 2
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Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card

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