(a) Interpretation: The type of intermolecular forces present in liquid state of xenon molecule must be explained. Concept Introduction: Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction. Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole. In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts. In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Question

A molecule shows peaks at 1379, 1327, 1249, 739 cm-1. Draw a diagram of the energy levels for such a molecule. Draw arrows for the possible transitions that could occur for the molecule. In the diagram imagine exciting an electron, what are its various options for getting back to the ground state? What process would promote radiation less decay? What do you expect for the lifetime of an electron in the T1 state? Why is phosphorescence emission weak in most substances? What could you do to a sample to enhance the likelihood that phosphorescence would occur over radiationless decay?

Answer 1

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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A molecule shows peaks at 1379, 1327, 1249, 739 cm-1. Draw a diagram of the energy levels for such a molecule. Draw arrows for the possible transitions that could occur for the molecule. In the diagram imagine exciting an electron, what are its various options for getting back to the ground state? What process would promote radiation less decay? What do you expect for the lifetime of an electron in the T1 state? Why is phosphorescence emission weak in most substances? What could you do to a sample to enhance the likelihood that phosphorescence would occur over radiationless decay?

Rank the indicated C—C bonds in increasing order of bond length. Explain as why to the difference.

Use IUPAC rules to name the following alkane

Answer 2

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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Answer 3

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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Answer 4

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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Answer 5

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 6

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Answer 7

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 14

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Answer 25

Ch. 14.2 - trong>Exercise 14.1 Calculate the total energy...Ch. 14.3 - Prob. 1CT Ch. 14.6 - trong>Exercise 14.2 Name the type of crystalline...Ch. 14 - ou seal a container half-filled with water. Which...Ch. 14 - xplain the following: You add 100mLof water to a...Ch. 14 - Prob. 3ALQ Ch. 14 - Prob. 4ALQ Ch. 14 - Prob. 5ALQ Ch. 14 - Prob. 6ALQ Ch. 14 - Prob. 7ALQ

Solution Summary: The author explains the type of intermolecular forces present in liquid state of xenon molecule.

Chapter 14 Solutions