(a) Interpretation: All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers. Concept Introduction: The stereocenter is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Question

Write structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?

Answer 1

Question

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

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Write structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?

Plan the synthesis of the following compound using the starting material provided and any other reagents needed as long as carbon based reagents have 3 carbons or less. Either the retrosynthesis or the forward synthesis (mechanisms are not required but will be graded if provided) will be accepted if all necessary reagents and intermediates are shown (solvents and temperature requirements are not needed unless specifically involved in the reaction, i.e. DMSO in the Swern oxidation or heat in the KMnO4 oxidation). H H

Hint These are benzene substitution reactions. ALCI3 and UV light are catalyst no part in reactions and triangle A means heating. A. Add ethyl for Et in benzene ring alkylation reaction EtCl = CH3CH2CL 1) EtC1 / AlCl3 / A ? B: Add Br to benzene ring ( substitution) 2) Br₂ / uv light ? C Add (CH3)2 CHCH2 in benzene ring ( substitution) (CH3)2CHCH,C1 / AICI, ?

Answer 2

Question

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

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Answer 3

Question

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

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Answer 4

Question

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

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Answer 5

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Answer 6

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Answer 7

Chapter 14, Problem 21P

Interpretation Introduction

(a)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Answer 8

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Answer 9

Interpretation Introduction

(b)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocenter is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different. The stereocenter may also be generated due to presence of asymmetric double bond.

Answer 10

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Answer 11

Interpretation Introduction

(c)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon. The chiral carbon is the carbon bearing all the four groups different.

Answer 12

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Answer 13

Interpretation Introduction

(d)

Interpretation:

All the stereocenters should be marked using asterisk in the given molecule and identify the number of possible stereoisomers.

Concept Introduction:

The stereocentre is generated in an organic compound due to presence of chiral carbon.

The chiral carbon is the carbon bearing all the four groups different.

Answer 14

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Ch. 14.1 - Prob. 14.1QC Ch. 14.2 - Problem 15-2 Assign priorities to the groups in...Ch. 14.2 - Problem 15-3 Assign an R or S configuration to the...Ch. 14.3 - Problem 15-4 3-Amino-2-butanol has two...Ch. 14.3 - Prob. 14.5QC Ch. 14.3 - Prob. 14.6QC Ch. 14 - 15-7 Answer true or false. The cis and trans...Ch. 14 - 15-8 What does the term “chiral” mean? Give an...Ch. 14 - 15-9 What does the term “achiral” mean? Give an...Ch. 14 - 15-10 Define the term “stereoisomer.” Name three...

Solution Summary: The author explains that the stereocenter is generated in an organic compound due to presence of chiral carbon.

Chapter 14 Solutions