Chemistry In Focus
6th Edition
ISBN: 9781305544727
Author: Tro
Publisher: Cengage
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Chapter 14, Problem 21E
Interpretation Introduction
Interpretation:
The relationship between the aging and oxidation is to be explained.
Concept introduction:
A molecule that contains unpaired electron(s) is called a free radical and radicals are highly reactive and toxic.
Free radicals are generated as a by-product from oxygen catabolism during the oxidative stress.
A free radical can be generated by the cleavage of a weak bond between electrons.
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Given the reaction R+ Q → P, indicate
(A). the rate law with respect to P:
(B). the rate law with respect to R:
(C). the rate law with respect to Q:
d[P]
dt
d[R]
dt
d[Q]
dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Chapter 14 Solutions
Chemistry In Focus
Ch. 14 - For the following redox reaction, identify the...Ch. 14 - Prob. 14.2YTCh. 14 - Prob. 1SCCh. 14 - What substance is the oxidizing agent in...Ch. 14 - Closely examine Figure 14.1 and explain why no...Ch. 14 - Prob. 1ECh. 14 - Explain the basic principle involved common...Ch. 14 - Prob. 3ECh. 14 - Prob. 4ECh. 14 - Prob. 5E
Ch. 14 - Can an oxidation reaction occur without a...Ch. 14 - Prob. 7ECh. 14 - Why is bromine reduced in the following reaction...Ch. 14 - What is an oxidizing agent? A reducing agent?Ch. 14 - Prob. 10ECh. 14 - Write equations for respiration and...Ch. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Give a thermodynamic argument for why it is more...Ch. 14 - Prob. 17ECh. 14 - Use chemical equations to explain how the molten...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Prob. 22ECh. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Draw Lewis structures for each chemical reaction,...Ch. 14 - Draw Lewis structures for each chemical reaction,...Ch. 14 - Prob. 27ECh. 14 - For each reaction, indicate which elements are...Ch. 14 - For each reaction, indicate which elements are...Ch. 14 - For each reaction, indicate which elements are...Ch. 14 - For each reaction, identify the oxidizing agent...Ch. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Prob. 34ECh. 14 - Which would you expect to be a better oxidizing...Ch. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - Sum each of the following oxidation and reduction...Ch. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Which of the following factors might affect the...Ch. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - Fossil fuel, nuclear, and hydroelectric power...Ch. 14 - The following diagram shows an electrochemical...Ch. 14 - The following diagram shows a molecular view of...
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