Concept explainers
(a)
Interpretation:
The given quantity is to be expressed in exponential notation. Also significant zeroes and digits are to be determined.
Concept introduction:
Significant figures of a number are the digits which carry meaningful contribution to its measurement resolution. The rightmost digit of the quantity is the most uncertain digit.
The number of certain and uncertain digit in a quantity is considered as significant figures. The digit with a higher number of significant figures has a higher certainty of measurement.
To determine the number of significant figures in a quantity following steps are followed.
1. The quantity must has a decimal point.
2. Start counting from the left and proceed towards the right until the first nonzero digit is encountered. All nonzero digit and the zeroes between two nonzero digits are considered as significant figures. For example, 0.0000765 has three significant figures and 7009 has four significant figures.
3. Zeroes after a decimal point are significant figures. For example, 42.0 have three significant figures.
4. Trailing zeroes that do nothing but are used to set a decimal point are non-significant figures. However, exponential notation can be used to avoid confusion. For example, 4300 has 3 significant figures. It can be expressed in scientific notation as
5. Zeroes present before a trailing decimal point are significant figures. For example, 3200 has only two significant figures but 3200. has 4 significant figures.
(b)
Interpretation:
The given quantity is to be expressed in exponential notation. Also significant zeroes and digits are to be determined.
Concept introduction:
Significant figures of a number are the digits which carry meaningful contribution to its measurement resolution. The rightmost digit of the quantity is the most uncertain digit.
The number of certain and uncertain digit in a quantity is considered as significant figures. The digit with a higher number of significant figures has a higher certainty of measurement.
To determine the number of significant figures in a quantity following steps are followed.
1. The quantity must has a decimal point.
2. Start counting from the left and proceed towards the right until the first nonzero digit is encountered. All nonzero digit and the zeroes between two nonzero digits are considered as significant figures. For example, 0.0000765 has three significant figures and 7009 has four significant figures.
3. Zeroes after a decimal point are significant figures. For example, 42.0 have three significant figures.
4. Trailing zeroes that do nothing but are used to set a decimal point are non-significant figures. However, exponential notation can be used to avoid confusion. For example, 4300 has 3 significant figures. It can be expressed in scientific notation as
5. Zeroes present before a trailing decimal point are significant figures. For example, 3200 has only two significant figures but 3200. has 4 significant figures.
(c)
Interpretation:
The given quantity is to be expressed in exponential notation. Also significant zeroes and digits are to be determined.
Concept introduction:
Significant figures of a number are the digits which carry meaningful contribution to its measurement resolution. The rightmost digit of the quantity is the most uncertain digit.
The number of certain and uncertain digit in a quantity is considered as significant figures. The digit with a higher number of significant figures has a higher certainty of measurement.
To determine the number of significant figures in a quantity following steps are followed.
1. The quantity must has a decimal point.
2. Start counting from the left and proceed towards the right until the first nonzero digit is encountered. All nonzero digit and the zeroes between two nonzero digits are considered as significant figures. For example, 0.0000765 has three significant figures and 7009 has four significant figures.
3. Zeroes after a decimal point are significant figures. For example, 42.0 have three significant figures.
4. Trailing zeroes that do nothing but are used to set a decimal point are non-significant figures. However, exponential notation can be used to avoid confusion. For example, 4300 has 3 significant figures. It can be expressed in scientific notation as
5. Zeroes present before a trailing decimal point are significant figures. For example, 3200 has only two significant figures but 3200. has 4 significant figures.
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Chapter 1 Solutions
CHEMISTRY MOLECULAR NATURE CONNECT ACCES
- Calculate the reaction rate for selenious acid, H2SeO3, if 0.1150 M I-1 decreases to 0.0770 M in 12.0 minutes. H2SeO3(aq) + 6I-1(aq) + 4H+1(aq) ⟶ Se(s) + 2I3-1(aq) + 3H2O(l)arrow_forwardProblem 5-31 Which of the following objects are chiral? (a) A basketball (d) A golf club (b) A fork (c) A wine glass (e) A spiral staircase (f) A snowflake Problem 5-32 Which of the following compounds are chiral? Draw them, and label the chirality centers. (a) 2,4-Dimethylheptane (b) 5-Ethyl-3,3-dimethylheptane (c) cis-1,4-Dichlorocyclohexane Problem 5-33 Draw chiral molecules that meet the following descriptions: (a) A chloroalkane, C5H11Cl (c) An alkene, C6H12 (b) An alcohol, C6H140 (d) An alkane, C8H18 Problem 5-36 Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How H3C CH3 many chirality centers does erythronolide B have? OH Identify them. H3C -CH3 OH Erythronolide B H3C. H3C. OH OH CH3arrow_forwardPLEASE HELP! URGENT! PLEASE RESPOND!arrow_forward
- 2. Propose a mechanism for this reaction. ہلی سے ملی N H (excess)arrow_forwardSteps and explanationn please.arrow_forwardProblem 5-48 Assign R or S configurations to the chirality centers in ascorbic acid (vitamin C). OH H OH HO CH2OH Ascorbic acid O H Problem 5-49 Assign R or S stereochemistry to the chirality centers in the following Newman projections: H Cl H CH3 H3C. OH H3C (a) H H H3C (b) CH3 H Problem 5-52 Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each: OH OH (a) CH3CHCH2CH2CHCH3 CH3 H3C. -OH (c) H3C CH3 (b) Problem 5-66 Assign R or S configurations to the chiral centers in cephalexin, trade-named Keflex, the most widely prescribed antibiotic in the United States. H2N H IHH S Cephalexin N. CH3 CO₂Harrow_forward
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