Pearson eText Basic Chemistry -- Instant Access (Pearson+)
6th Edition
ISBN: 9780135765982
Author: Karen Timberlake, William Timberlake
Publisher: PEARSON+
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Question
Chapter 1.4, Problem 17PP
Interpretation Introduction
To determine:The numerical value of the given expression
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 1 Solutions
Pearson eText Basic Chemistry -- Instant Access (Pearson+)
Ch. 1.1 - In every chapter. odd-numbered exercises in the...Ch. 1.1 - In every chapter. odd-numbered exercises in the...Ch. 1.1 - Prob. 3PPCh. 1.1 - Prob. 4PPCh. 1.1 - In every chapter. odd-numbered exercises in the...Ch. 1.1 - Prob. 6PPCh. 1.2 - Identify each activity, a to f, as an observation,...Ch. 1.2 - Identify each activity, a to f. as an observation,...Ch. 1.2 - Identify each of the following as an observation,...Ch. 1.2 - Identify each of the following as an observation,...
Ch. 1.3 - Prob. 11PPCh. 1.3 - What are four things that would make it difficult...Ch. 1.3 - Prob. 13PPCh. 1.3 - Prob. 14PPCh. 1.4 - What is the place value for the bold digit? a....Ch. 1.4 - What is the place value for the bold digit? a....Ch. 1.4 - Prob. 17PPCh. 1.4 - Prob. 18PPCh. 1.4 - Prob. 19PPCh. 1.4 - Prob. 20PPCh. 1.4 - Use the following graph for problems 1.21 and...Ch. 1.4 - Use the following graph for problems 1.21 and...Ch. 1.4 - a. A clinic had 25 patients on Friday morning....Ch. 1.4 - a. At a local hospital. 35 babies were born in...Ch. 1.4 - Prob. 25PPCh. 1.4 - Prob. 26PPCh. 1.5 - Prob. 27PPCh. 1.5 - Write each of the following in scientific...Ch. 1.5 - Prob. 29PPCh. 1.5 - Write each of the following as a standard number:...Ch. 1.5 - Prob. 31PPCh. 1.5 - Prob. 32PPCh. 1.5 - Prob. 33PPCh. 1.5 - Prob. 34PPCh. 1 - The chapter sections to review are shown in...Ch. 1 - Prob. 36UTCCh. 1 - Prob. 37UTCCh. 1 - Prob. 38UTCCh. 1 - Prob. 39UTCCh. 1 - Prob. 40UTCCh. 1 - Prob. 41UTCCh. 1 - Prob. 42UTCCh. 1 - Select the correct phrase(s) to complete the...Ch. 1 - Select the correct phrase(s) to complete the...Ch. 1 - Prob. 45APPCh. 1 - Prob. 46APPCh. 1 - Prob. 47APPCh. 1 - Prob. 48APPCh. 1 - Evaluate each of the following: (1.4)...Ch. 1 - Prob. 50APPCh. 1 - A bag of gumdrops contains 16 orange gumdrops, 8...Ch. 1 - Prob. 52APPCh. 1 - Write each of the following in scientific...Ch. 1 - Write each of the following in scientific...Ch. 1 - Prob. 55APPCh. 1 - Write each of the following as a standard number:...Ch. 1 - Prob. 57APPCh. 1 - Prob. 58APPCh. 1 - Prob. 59CPCh. 1 - Prob. 60CPCh. 1 - Prob. 61CPCh. 1 - The following problems are related to the topics...Ch. 1 - The following problems are related to the topics...Ch. 1 - Prob. 64CP
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