Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 14, Problem 14E
What is Henry’s law? For what kinds of calculations is Henry’s law useful?
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Chapter 14 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 14 - Which compound is most soluble in octane (C8H18)?...Ch. 14 - Prob. 2SAQCh. 14 - A 500.0-mL sample of pure water is allowed to come...Ch. 14 - Prob. 4SAQCh. 14 - Prob. 5SAQCh. 14 - Prob. 6SAQCh. 14 - What is the vapor pressure of an aqueous ethylene...Ch. 14 - Prob. 8SAQCh. 14 - What mass of glucose (C6H12O6) should you dissolve...Ch. 14 - Which aqueous solution has the highest boiling...
Ch. 14 - The osmotic pressure of a solution containing 22.7...Ch. 14 - The enthalpy of solution for NaOH is -44.6 kJ/mol....Ch. 14 - A 2.4-m aqueous solution of an ionic compound with...Ch. 14 - A solution is an equimolar mixture of two volatile...Ch. 14 - An aqueous solution is in equilibrium with a...Ch. 14 - What is a solution? What are the solute and...Ch. 14 - What does it mean when we say that a substance is...Ch. 14 - Why do two ideal gases thoroughly mix when...Ch. 14 - Prob. 4ECh. 14 - Prob. 5ECh. 14 - Explain how the relative strengths of...Ch. 14 - What does the statement like dissolves like mean...Ch. 14 - Prob. 8ECh. 14 - What is the heat of hydration(Hhydration)? How...Ch. 14 - Prob. 10ECh. 14 - How does temperature affect the solubility of a...Ch. 14 - Prob. 12ECh. 14 - How does pressure affect the solubility of a gas...Ch. 14 - What is Henry’s law? For what kinds of...Ch. 14 - Prob. 15ECh. 14 - How are parts by mass and parts by volume used in...Ch. 14 - Prob. 17ECh. 14 - What is Raoult’s law? For what kind of...Ch. 14 - Explain the difference between an ideal and a...Ch. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - What are colligative properties?Ch. 14 - Prob. 23ECh. 14 - Explain the significance of the van’t Hoff factor...Ch. 14 - Prob. 25ECh. 14 - Pick an appropriate solvent from Table 13.3 to...Ch. 14 - Which molecule would you expect to be more soluble...Ch. 14 - Prob. 28ECh. 14 - Prob. 29ECh. 14 - Prob. 30ECh. 14 - When ammonium chloride (NH4Cl) is dissolved in...Ch. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Use the given data to calculate the heats of...Ch. 14 - Lithium iodide has a lattice energy of...Ch. 14 - Prob. 36ECh. 14 - A solution contains 25 g of NaCl per 100.0 g of...Ch. 14 - A solution contains 32 g of KNO3 per 100.0 g of...Ch. 14 - Prob. 39ECh. 14 - A KCI solution containing 42 g of KCI per 100.0 g...Ch. 14 - Some laboratory procedures involving...Ch. 14 - A person preparing a fish tank fills the tank with...Ch. 14 - Prob. 43ECh. 14 - Scuba divers breathing air at increased pressure...Ch. 14 - Calculate the mass of nitrogen dissolved at room...Ch. 14 - Use Henry’s law to determine the molar solubility...Ch. 14 - An aqueous NaCl solution is made using 112 g of...Ch. 14 - Prob. 48ECh. 14 - To what volume should you dilute 50.0 mL of a...Ch. 14 - Prob. 50ECh. 14 - Silver nitrate solutions are used to plate silver...Ch. 14 - Prob. 52ECh. 14 - Prob. 53ECh. 14 - Prob. 54ECh. 14 - You can purchase nitric acid in a concentrated...Ch. 14 - You can purchase hydrochloric acid in a...Ch. 14 - Prob. 57ECh. 14 - Prob. 58ECh. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - A beaker contains 100.0 mL of pure water. A second...Ch. 14 - Which solution has the highest vapor pressure? a....Ch. 14 - Calculate the vapor pressure of a solution...Ch. 14 - A solution contains naphthalene (C10H8) dissolved...Ch. 14 - A solution contains 50.0 g of heptane (C7H16) and...Ch. 14 - A solution contains a mixture of pentane and...Ch. 14 - A solution contains 4.08 g of chloroform (C3H8O3)...Ch. 14 - A solution of methanol and water has a mole...Ch. 14 - Prob. 73ECh. 14 - An ethylene glycol solution contains 21.2 g of...Ch. 14 - Calculate the freezing point and melting point of...Ch. 14 - Calculate the freezing point and melting point of...Ch. 14 - An aqueous solution containing 17.5 g of an...Ch. 14 - An aqueous solution containing 35.9 g of an...Ch. 14 - Calculate the osmotic pressure of a solution...Ch. 14 - Prob. 80ECh. 14 - A solution containing 27.55 mg of an unknown...Ch. 14 - Prob. 82ECh. 14 - Calculate the freezing point and boiling point...Ch. 14 - Calculate the freezing point and boiling point in...Ch. 14 - What mass of salt (NaCl) should you add to 1.00 L...Ch. 14 - Prob. 86ECh. 14 - Use the van’t Hoff factors in Table 13.7 to...Ch. 14 - Prob. 88ECh. 14 - A 1.2-m aqueous solution of an ionic compound with...Ch. 14 - A 0.95-m aqueous solution of an ionic compound...Ch. 14 - Prob. 91ECh. 14 - Prob. 92ECh. 14 - Prob. 93ECh. 14 - An aqueous CaCl2 solution has a vapor pressure of...Ch. 14 - Prob. 95ECh. 14 - Prob. 96ECh. 14 - Potassium perchlorate (KClO4) has a lattice energy...Ch. 14 - Sodium hydroxide (NaOH) has a lattice energy of...Ch. 14 - Prob. 99ECh. 14 - Prob. 100ECh. 14 - Prob. 101ECh. 14 - Water softeners often replace calcium ions in hard...Ch. 14 - Prob. 103ECh. 14 - Prob. 104ECh. 14 - Prob. 105ECh. 14 - Prob. 106ECh. 14 - An isotonic solution contains 0.90% NaCl mass to...Ch. 14 - Prob. 108ECh. 14 - Prob. 109ECh. 14 - When HNO2 dissolves in water, it partially...Ch. 14 - Prob. 111ECh. 14 - Prob. 112ECh. 14 - Prob. 113ECh. 14 - Distillation is a method of purification based on...Ch. 14 - Prob. 115ECh. 14 - Find the mass of urea (CH4N2O) needed to prepare...Ch. 14 - A solution contains 10.05 g of unknown compound...Ch. 14 - Prob. 118ECh. 14 - Prob. 119ECh. 14 - Prob. 120ECh. 14 - The small bubbles that form on the bottom of a...Ch. 14 - The vapor above a mixture of pentane and hexane at...Ch. 14 - A 1.10-g sample contains only glucose (C6H12O6)...Ch. 14 - Prob. 124ECh. 14 - Two alcohols, isopropyl alcohol and propyl...Ch. 14 - A metal, M, of atomic mass 96 amu reacts with...Ch. 14 - Prob. 127ECh. 14 - Prob. 128ECh. 14 - A solution is prepared by dissolving 11.60 g of a...Ch. 14 - Substance A is a nonpolar liquid and has only...Ch. 14 - Prob. 131ECh. 14 - Prob. 132ECh. 14 - Prob. 133ECh. 14 - Prob. 134E
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- Use the References to access important values if needed for this question. What is the IUPAC name of each of the the following? 0 CH3CHCNH₂ CH3 CH3CHCNHCH2CH3 CH3arrow_forwardYou have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…arrow_forwardb) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppmarrow_forward
- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY