Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 14, Problem 14A.5E
Interpretation Introduction
Interpretation:
Number of links in the chain has to be estimated.
Concept introduction:
The number of links in the chain can be calculated using following formula,
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Students have asked these similar questions
Consider the following two acid-base reactions:
OH
OHI
Based on what you know about the compounds and their acidity, which
direction would you expect both of these reactions to proceed? Show
your reasoning.
A pKa table has been provided in case you need it.
Functional group
Example
pka
CHA
-50
Alkane
-35
Amine
: NH3
Alkyne
RH
25
Water
HO-H
169
16
10
Protonated
amines
NH
10
5
Carboxylic
acids
OH
Hydrochloric
acid
HCI
A chemist intends to run the following reaction on the three substrates shown below:
H₂O
R-CI
product
room temp.
Cl
Cl
(1)
(2)
(3)
They find one will react quickly, one slowly, and one will not react at all. Which is which, and why?
HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?
NH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.
Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
Chapter 14 Solutions
Elements Of Physical Chemistry
Ch. 14 - Prob. 14A.1STCh. 14 - Prob. 14A.2STCh. 14 - Prob. 14A.4STCh. 14 - Prob. 14A.5STCh. 14 - Prob. 14B.2STCh. 14 - Prob. 14B.3STCh. 14 - Prob. 14A.1ECh. 14 - Prob. 14A.2ECh. 14 - Prob. 14A.3ECh. 14 - Prob. 14A.4E
Ch. 14 - Prob. 14A.5ECh. 14 - Prob. 14A.6ECh. 14 - Prob. 14A.7ECh. 14 - Prob. 14B.1ECh. 14 - Prob. 14B.2ECh. 14 - Prob. 14B.3ECh. 14 - Prob. 14B.4ECh. 14 - Prob. 14.1DQCh. 14 - Prob. 14.2DQCh. 14 - Prob. 14.3DQCh. 14 - Prob. 14.4DQCh. 14 - Prob. 14.5DQCh. 14 - Prob. 14.6DQCh. 14 - Prob. 14.1PCh. 14 - Prob. 14.2PCh. 14 - Prob. 14.3PCh. 14 - Prob. 14.5PCh. 14 - Prob. 14.6PCh. 14 - Prob. 14.7P
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