(a)
Interpretation:
The equation representing the reaction of butanoic anhydride with propanol has to be written and the IUPAC name of the products has to be provided.
Concept Introduction:
Acid anhydrides are compounds with the formula,
Acid anhydrides react with an alcohol to produce an ester and a
The general reaction of acyl group transfer reaction between an alcohol and an acid anhydride is written as,
The acyl group of the acid anhydride is transferred to the oxygen of the alcohol and the products of esters are produced. The carboxylic acid product is omitted.
Nomenclature of Esters
The simplest method to name an ester starts by identifying the carboxylic acid and alcohol.
The first part of the name of an ester is the alkyl or aryl group of the alcohol
- The name of the parent alcohol is identified and the name of the corresponding alkyl or aryl group is written.
The second part of the name is derived from the carboxylic acid
- The name of the parent carboxylic acid is identified and the suffix -ic is replaced with –ate.
(b)
Interpretation:
The equation representing the reaction of pentanoic anhydride with propanol has to be written and the IUPAC name of the products has to be provided.
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
The equation representing the reaction of methanoic anhydride with propanol has to be written and the IUPAC name of the products has to be provided.
Concept Introduction:
Refer to part (a).
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Chapter 14 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY
- In addition to the separation techniques used in this lab (magnetism, evaporation, and filtering), there are other commonly used separation techniques. Some of these techniques are:Distillation – this process is used to separate components that have significantly different boiling points. The solution is heated and the lower boiling point substance is vaporized first. The vapor can be collected and condensed and the component recovered as a pure liquid. If the temperature of the mixture is then raised, the next higher boiling component will come off and be collected. Eventually only non-volatile components will be left in the original solution.Centrifugation – a centrifuge will separate mixtures based on their mass. The mixture is placed in a centrifuge tube which is then spun at a high speed. Heavier components will settle at the bottom of the tube while lighter components will be at the top. This is the technique used to separate red blood cells from blood plasma.Sieving – this is…arrow_forwardBriefly describe a eutectic system.arrow_forward13.53 Draw all stereoisomers formed when each compound is treated with HBr in the presence of peroxides. a. b. C.arrow_forward
- Nonearrow_forwardNonearrow_forwardman Campus Depa (a) Draw the three products (constitutional isomers) obtained when 2-methyl-3-hexene reacts with water and a trace of H2SO4. Hint: one product forms as the result of a 1,2-hydride shift. (1.5 pts) This is the acid-catalyzed alkene hydration reaction.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)