GENERAL,ORGANIC,+BIOCHEMISTRY
GENERAL,ORGANIC,+BIOCHEMISTRY
10th Edition
ISBN: 9781260148954
Author: Denniston
Publisher: RENT MCG
Question
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Chapter 14, Problem 14.96QP

(a)

Interpretation Introduction

Interpretation:

The equation representing the reaction of butanoic anhydride with propanol has to be written and the IUPAC name of the products has to be provided.

Concept Introduction:

Acid anhydrides are compounds with the formula,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14, Problem 14.96QP , additional homework tip  1

Acid anhydrides react with an alcohol to produce an ester and a carboxylic acid.  This is an example of an acyl group transfer reaction.

The general reaction of acyl group transfer reaction between an alcohol and an acid anhydride is written as,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14, Problem 14.96QP , additional homework tip  2

The acyl group of the acid anhydride is transferred to the oxygen of the alcohol and the products of esters are produced.  The carboxylic acid product is omitted.

Nomenclature of Esters

The simplest method to name an ester starts by identifying the carboxylic acid and alcohol.

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14, Problem 14.96QP , additional homework tip  3

The first part of the name of an ester is the alkyl or aryl group of the alcohol

  • The name of the parent alcohol is identified and the name of the corresponding alkyl or aryl group is written.

The second part of the name is derived from the carboxylic acid

  • The name of the parent carboxylic acid is identified and the suffix -ic is replaced with –ate.

(b)

Interpretation Introduction

Interpretation:

The equation representing the reaction of pentanoic anhydride with propanol has to be written and the IUPAC name of the products has to be provided.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The equation representing the reaction of methanoic anhydride with propanol has to be written and the IUPAC name of the products has to be provided.

Concept Introduction:

Refer to part (a).

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Chapter 14 Solutions

GENERAL,ORGANIC,+BIOCHEMISTRY

Ch. 14.1 - Prob. 14.5PPCh. 14.1 - Prob. 14.6PPCh. 14.2 - Prob. 14.7PPCh. 14.2 - Prob. 14.8PPCh. 14.2 - Prob. 14.9PPCh. 14.2 - Prob. 14.7QCh. 14.2 - Prob. 14.8QCh. 14.3 - Prob. 14.10PPCh. 14.3 - Write the common and IUPAC names for each of the...Ch. 14.3 - Prob. 14.9QCh. 14.3 - Prob. 14.10QCh. 14 - Prob. 14.11QPCh. 14 - Prob. 14.12QPCh. 14 - Prob. 14.13QPCh. 14 - Prob. 14.14QPCh. 14 - Prob. 14.15QPCh. 14 - Prob. 14.16QPCh. 14 - Prob. 14.17QPCh. 14 - Which member in each of the following pairs is...Ch. 14 - Prob. 14.19QPCh. 14 - Prob. 14.20QPCh. 14 - Prob. 14.21QPCh. 14 - Prob. 14.22QPCh. 14 - Prob. 14.23QPCh. 14 - Prob. 14.24QPCh. 14 - Prob. 14.25QPCh. 14 - Prob. 14.26QPCh. 14 - Prob. 14.27QPCh. 14 - Prob. 14.28QPCh. 14 - Prob. 14.29QPCh. 14 - Prob. 14.30QPCh. 14 - Prob. 14.31QPCh. 14 - Prob. 14.32QPCh. 14 - Prob. 14.33QPCh. 14 - Prob. 14.34QPCh. 14 - Prob. 14.35QPCh. 14 - Prob. 14.36QPCh. 14 - Prob. 14.37QPCh. 14 - Prob. 14.38QPCh. 14 - Prob. 14.39QPCh. 14 - Prob. 14.40QPCh. 14 - Prob. 14.41QPCh. 14 - Prob. 14.42QPCh. 14 - Prob. 14.43QPCh. 14 - Prob. 14.44QPCh. 14 - Prob. 14.45QPCh. 14 - Prob. 14.46QPCh. 14 - Prob. 14.47QPCh. 14 - Prob. 14.48QPCh. 14 - Write an equation representing the oxidation of...Ch. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.54QPCh. 14 - Write an equation representing the neutralization...Ch. 14 - Prob. 14.56QPCh. 14 - Prob. 14.57QPCh. 14 - Prob. 14.58QPCh. 14 - Prob. 14.59QPCh. 14 - Prob. 14.60QPCh. 14 - Prob. 14.61QPCh. 14 - Prob. 14.62QPCh. 14 - Prob. 14.63QPCh. 14 - Draw condensed formulas for each of the following...Ch. 14 - Prob. 14.65QPCh. 14 - Prob. 14.66QPCh. 14 - Prob. 14.67QPCh. 14 - Prob. 14.68QPCh. 14 - Prob. 14.69QPCh. 14 - Prob. 14.70QPCh. 14 - Prob. 14.71QPCh. 14 - Prob. 14.72QPCh. 14 - Prob. 14.73QPCh. 14 - Prob. 14.74QPCh. 14 - Prob. 14.75QPCh. 14 - Prob. 14.76QPCh. 14 - Prob. 14.77QPCh. 14 - Prob. 14.78QPCh. 14 - Prob. 14.79QPCh. 14 - Prob. 14.80QPCh. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - Prob. 14.83QPCh. 14 - Prob. 14.84QPCh. 14 - Prob. 14.85QPCh. 14 - Prob. 14.86QPCh. 14 - Prob. 14.87QPCh. 14 - Prob. 14.88QPCh. 14 - Prob. 14.89QPCh. 14 - Prob. 14.90QPCh. 14 - Prob. 14.91QPCh. 14 - Prob. 14.92QPCh. 14 - Prob. 14.93QPCh. 14 - Prob. 14.94QPCh. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - Prob. 14.97QPCh. 14 - What is meant by a phosphoanhydride bond? Ch. 14 - Prob. 14.99QPCh. 14 - Prob. 14.100QPCh. 14 - Prob. 14.101QPCh. 14 - Prob. 14.102QPCh. 14 - Prob. 14.103QPCh. 14 - Prob. 2MCPCh. 14 - Consider the Chapter Map, and explain the...Ch. 14 - Prob. 4MCPCh. 14 - Prob. 6MCPCh. 14 - Triglycerides are the major lipid storage form in...Ch. 14 - Prob. 10MCPCh. 14 - Acetyl coenzyme A (acetyl CoA) can serve as a...Ch. 14 - Prob. 12MCP
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