
Concept explainers
(a)
Interpretation:
In accordance with the given conditions the number of possible arrangements and the entropy for the given set up has to be calculated.
Concept Introduction:
A
Where
The entropy and thermodynamic probability is related by Boltzmann equation. As the number of possible arrangements increases the entropy also increases.
Where,
(b)
Interpretation:
In accordance with the given conditions the number of possible arrangements and the entropy for the given set up has to be calculated.
Concept Introduction:
A thermodynamic system can have degenerate and non degenerate energy levels. There can be different possible arrangements of the particles in the various energy levels. These possible arrangements are defined as thermodynamic probability
Where
The entropy and thermodynamic probability is related by Boltzmann equation. As the number of possible arrangements increases the entropy also increases.
Where,
(c)
Interpretation:
In accordance with the given conditions the number of possible arrangements and the entropy for the given set up has to be calculated.
Concept Introduction:
A thermodynamic system can have degenerate and non degenerate energy levels. There can be different possible arrangements of the particles in the various energy levels. These possible arrangements are defined as thermodynamic probability
Where
The entropy and thermodynamic probability is related by Boltzmann equation. As the number of possible arrangements increases the entropy also increases.
Where,

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Chapter 14 Solutions
Chemistry Atoms First, Second Edition
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