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PRACTICE 14.7 In the industrial synthesis of hydrogen, mixtures of CO and H2 are enriched in H2 by allowing the CO to react with steam. The chemical equation for this water-gas shift reaction is
What is the value of KP, at 700 K if the partial pressures in an equilibrium mixture at700 K are 1.31 atm of CO, 10.0 atm of H2O, 6.12 atm of CO2, and 20.3 atm of H2?
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Chapter 14 Solutions
Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
- 2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forwardE17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.arrow_forward
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