Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
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Chapter 14, Problem 14.3P
Interpretation Introduction

Interpretation:

Oxidizing and reducing agent and balanced half-reaction for below reaction have to be determined.

  Na(s)+H2ONa++OH+12H2(g)

Concept Introduction:

Oxidation refers to phenomenon of loss of electrons, loss of electropositive H and gain of electronegative O. Substance that gets oxidized is termed as reducing agent.

Reduction is process that involves gain of electrons, gain of H or loss of electronegative O atom. Substance that gets reduced is termed as oxidizing agent.

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4. Refer to the data below to answer the following questions: The octapeptide saralasin is a specific antagonist of angiotensin II. A derivative of saralasin is used therapeutically as an antihypertensive. Amino acid analysis of saralasin show the presence of the following amino acids: Ala, Arg, His, Pro, Sar, Tyr, Val, Val A.Sar is the abbreviation for sarcosine, N-methyl aminoethanoic acid. Draw the structure of sarcosine. B. N-Terminal analysis by the Edman method shows saralasin contains sarcosine at the N-terminus. Partial hydrolysis of saralasin with dilute hydrochloric acid yields the following fragments: Tyr-Val-His Sar-Arg-Val His-Pro-Ala Val-Tyr-Val Arg-Val-Tyr What is the structure of saralasin?
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