EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
7th Edition
ISBN: 8220106637203
Author: Chang
Publisher: YUZU
Question
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Chapter 14, Problem 14.31QP

(a)

Interpretation Introduction

Interpretation:

A plot of potential-energy-versus-reaction-progress for the given reaction has to be sketched.

Concept introduction:

The plot of potential-energy-versus-reaction-progress enables the study of endothermic, exothermic reactions.

The co-ordinates in the plot of potential-energy-versus-reaction-progress should be plotted as follows.

  • The progress of reaction in time has to be plotted in X-axis of the plot.
  • The potential energy of the reaction has to be plotted in Y-axis of the plot.

ΔHis enthanpy change.

It refers to the amount of heat absorbed or released in a reaction.

The signs of ΔH:

If the value of ΔH is less than zero, then the -ve sign of the value represents that the heat is released out by the system and it is known as Exothermicprocess(Exo=out;thermic=heat).

If the value of ΔH is more than zero, then the +ve sign of the value represents that the heat is absorbed in by the system and it is known as Endothermicprocess(Endo=in;thermic=heat).

(b)

Interpretation Introduction

Interpretation:

A plot of potential-energy-versus-reaction-progress for the given reaction has to be sketched.

Concept introduction:

The plot of potential-energy-versus-reaction-progress enables the study of endothermic, exothermic reactions.

The co-ordinates in the plot of potential-energy-versus-reaction-progress should be plotted as follows.

  • The progress of reaction in time has to be plotted in X-axis of the plot.
  • The potential energy of the reaction has to be plotted in Y-axis of the plot.

ΔHis enthanpy change.

It refers to the amount of heat absorbed or released in a reaction.

The signs of ΔH:

If the value of ΔH is less than zero, then the -ve sign of the value represents that the heat is released out by the system and it is known as Exothermicprocess(Exo=out;thermic=heat).

If the value of ΔH is more than zero, then the +ve sign of the value represents that the heat is absorbed in by the system and it is known as Endothermicprocess(Endo=in;thermic=heat).

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Chapter 14 Solutions

EBK GENERAL CHEMISTRY: THE ESSENTIAL CO

Ch. 14.4 - Practice Exercise The first-order rate constant...Ch. 14.4 - Review of Concepts (a) What can you deduce about...Ch. 14.5 - Practice Exercise The reaction between NO2 and CO...Ch. 14.5 - Prob. 1RCCh. 14.6 - Prob. 1RCCh. 14 - Prob. 14.1QPCh. 14 - 15.2 Explain the difference between physical...Ch. 14 - Prob. 14.3QPCh. 14 - Prob. 14.4QPCh. 14 - Prob. 14.5QPCh. 14 - 14.6 Consider the reaction Suppose that at a...Ch. 14 - Prob. 14.7QPCh. 14 - 14.8 What are the units for the rate constants of...Ch. 14 - Prob. 14.9QPCh. 14 - Prob. 14.10QPCh. 14 - Prob. 14.11QPCh. 14 - Prob. 14.13QPCh. 14 - Prob. 14.14QPCh. 14 - Prob. 14.15QPCh. 14 - Prob. 14.16QPCh. 14 - Prob. 14.17QPCh. 14 - Prob. 14.18QPCh. 14 - Prob. 14.19QPCh. 14 - Prob. 14.20QPCh. 14 - 14.21 What is the half-life of a compound if 75...Ch. 14 - 14.22 The thermal decomposition of phosphine (PH3)...Ch. 14 - Prob. 14.23QPCh. 14 - Prob. 14.24QPCh. 14 - 14.25 Consider the first-order reaction A → B...Ch. 14 - Prob. 14.26QPCh. 14 - 14.27 Define activation energy. What role does...Ch. 14 - Prob. 14.28QPCh. 14 - Prob. 14.29QPCh. 14 - 14.30 As we know, methane burns readily in oxygen...Ch. 14 - Prob. 14.31QPCh. 14 - Prob. 14.32QPCh. 14 - Prob. 14.33QPCh. 14 - Prob. 14.34QPCh. 14 - Prob. 14.35QPCh. 14 - Prob. 14.36QPCh. 14 - Prob. 14.37QPCh. 14 - 14.38 The rate at which tree crickets chirp is 2.0...Ch. 14 - 14.39 The diagram here describes the initial state...Ch. 14 - Prob. 14.40QPCh. 14 - Prob. 14.41QPCh. 14 - Prob. 14.42QPCh. 14 - 14.43 Explain why termolecular reactions are...Ch. 14 - 14.44 What is the rate-determining step of a...Ch. 14 - Prob. 14.45QPCh. 14 - Prob. 14.46QPCh. 14 - Prob. 14.47QPCh. 14 - Prob. 14.48QPCh. 14 - Prob. 14.49QPCh. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.53QPCh. 14 - Prob. 14.54QPCh. 14 - Prob. 14.55QPCh. 14 - Prob. 14.56QPCh. 14 - Prob. 14.57QPCh. 14 - Prob. 14.58QPCh. 14 - Prob. 14.59QPCh. 14 - Prob. 14.60QPCh. 14 - Prob. 14.61QPCh. 14 - Prob. 14.62QPCh. 14 - Prob. 14.63QPCh. 14 - Prob. 14.64QPCh. 14 - Prob. 14.65QPCh. 14 - 14.66 The decomposition of N2O to N2 and O2 is a...Ch. 14 - Prob. 14.67QPCh. 14 - Prob. 14.68QPCh. 14 - 14.69 Consider the zero-order reaction a → B....Ch. 14 - Prob. 14.70QPCh. 14 - Prob. 14.72QPCh. 14 - Prob. 14.73QPCh. 14 - Prob. 14.74QPCh. 14 - Prob. 14.75QPCh. 14 - Prob. 14.76QPCh. 14 - Prob. 14.77QPCh. 14 - Prob. 14.78QPCh. 14 - Prob. 14.79QPCh. 14 - Prob. 14.80QPCh. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - 14.83 When a mixture of methane and bromine is...Ch. 14 - 14.84 Consider this elementary step: (a)...Ch. 14 - Prob. 14.85QPCh. 14 - Prob. 14.86QPCh. 14 - 14.87 In recent years ozone in the stratosphere...Ch. 14 - Prob. 14.88QPCh. 14 - Prob. 14.90QPCh. 14 - Prob. 14.91QPCh. 14 - Prob. 14.92QPCh. 14 - Prob. 14.93QPCh. 14 - Prob. 14.94QPCh. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - Prob. 14.97QPCh. 14 - Prob. 14.98QPCh. 14 - Prob. 14.100QPCh. 14 - Prob. 14.101QPCh. 14 - 14.102 Consider the potential energy profiles...Ch. 14 - Prob. 14.103QPCh. 14 - Prob. 14.104QPCh. 14 - 14.105 The activation energy for the...Ch. 14 - Prob. 14.106QPCh. 14 - Prob. 14.107SPCh. 14 - Prob. 14.108SPCh. 14 - Prob. 14.109SPCh. 14 - Prob. 14.110SPCh. 14 - Prob. 14.111SPCh. 14 - Prob. 14.112SPCh. 14 - Prob. 14.113SPCh. 14 - Prob. 14.114SPCh. 14 - Prob. 14.115SPCh. 14 - 14.116 To prevent brain damage, a drastic medical...Ch. 14 - Prob. 14.117SPCh. 14 - Prob. 14.118SP
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