(a) Interpretation: The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation. Concept introduction: The Benesi-Hildebrand equation is: b Δ A = 1 Δ ε K f C M . 1 C L + 1 Δ ε C M b − length of the solution light passes through ΔA − difference between absorbance with and without the ligand present Δe − difference of the molar absorptivities of complex and metal ion. K f − formation constant C M − concentration of metal ion C L − concentration of ligand.

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Answer 1

Question

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

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Answer 2

Question

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Answer 6

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Answer 7

Chapter 14, Problem 14.23QAP

Interpretation Introduction

(a)

Interpretation:

The formation constant and the difference in molar absorptivities at 470 nm should be determined using linear regression and the Benesi-Hildebrand equation.

Concept introduction:

The Benesi-Hildebrand equation is:

bΔA=1ΔεKfCM.1CL+1ΔεCM

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The values of K_f and Δe should be determined using non-linear regression.

Concept introduction:

ΔAb=ΔεKfCLCM1+KfCL

b − length of the solution light passes through

ΔA − difference between absorbance with and without the ligand present

Δe − difference of the molar absorptivities of complex and metal ion.

K_f − formation constant

C_M − concentration of metal ion

C_L − concentration of ligand.

Answer 10

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Answer 11

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Answer 12

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Answer 13

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