The concentration of a solution of tryptamine under given conditions should be determined. Concept introduction: The rate of the reaction is given by, d [ P ] d t = k 2 [ E ] 0 [ S ] K m + [ S ] [P] − product concentration k 2 − dissociation constant for enzyme substrate complex into products and free enzyme. [E] 0 − initial enzyme concentration [S] − substrate concentration Km − Michaelis constant

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

Answer 1

Question

Chapter 14, Problem 14.15QAP

Interpretation Introduction

Interpretation:

The concentration of a solution of tryptamine under given conditions should be determined.

Concept introduction:

The rate of the reaction is given by,

d[P]dt=k2[E]0[S]Km+[S]

[P] − product concentration

k₂ − dissociation constant for enzyme substrate complex into products and free enzyme.

[E]₀ − initial enzyme concentration

[S] − substrate concentration

Km − Michaelis constant

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