Chapter 14, Problem 14.111QP

Consider the potential energy diagrams for two types of reactions $\text{A}\rightleftharpoons \text{B}$. In each case, answer the following questions for the system at equilibrium. (a) How would a catalyst affect the forward and reverse rates of the reaction? (b) How would a catalyst affect the energies of the reactant and product? (c) How would an increase in temperature affect the equilibrium constant? (d) If the only effect of a catalyst is to lower the activation energies for the forward and reverse reactions, show that the equilibrium constant remains unchanged if a catalyst is added to the reacting mixture.