EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 14, Problem 14.10P
Interpretation Introduction

(a)

Interpretation:

The explanation of the statement, “The hydration of alkyne is not a reasonable preparative method for propanal” is to be stated.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The explanation of the statement, “The hydration of alkyne is not a reasonable preparative method for 2, 2, 4, 4-tetramethylpentan-3-one” is to be stated.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

Interpretation Introduction

(c)

Interpretation:

The explanation of the statement, “The hydration of alkyne is not a reasonable preparative method for cyclohexanone ” is to be stated.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

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