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Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 14, Problem 127E
Interpretation Introduction
Interpretation:
“ molality of ” should be identified.
Concept introduction:
molality of a solution is the number of moles divided by mass of solvent in kilogram and can be expressed as follows;
Expert Solution & Answer
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Students have asked these similar questions
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 14 Solutions
Chemistry: Structure and Properties
Ch. 14 - Which compound is most soluble in octane (C8H18)?...Ch. 14 - Prob. 2SAQCh. 14 - A 500.0-mL sample of pure water is allowed to come...Ch. 14 - Prob. 4SAQCh. 14 - Prob. 5SAQCh. 14 - Prob. 6SAQCh. 14 - What is the vapor pressure of an aqueous ethylene...Ch. 14 - Prob. 8SAQCh. 14 - What mass of glucose (C6H12O6) should you dissolve...Ch. 14 - Which aqueous solution has the highest boiling...
Ch. 14 - The osmotic pressure of a solution containing 22.7...Ch. 14 - The enthalpy of solution for NaOH is -44.6 kJ/mol....Ch. 14 - A 2.4-m aqueous solution of an ionic compound with...Ch. 14 - A solution is an equimolar mixture of two volatile...Ch. 14 - An aqueous solution is in equilibrium with a...Ch. 14 - What is a solution? What are the solute and...Ch. 14 - What does it mean when we say that a substance is...Ch. 14 - Why do two ideal gases thoroughly mix when...Ch. 14 - Prob. 4ECh. 14 - Prob. 5ECh. 14 - Explain how the relative strengths of...Ch. 14 - What does the statement like dissolves like mean...Ch. 14 - Prob. 8ECh. 14 - What is the heat of hydration(Hhydration)? How...Ch. 14 - Prob. 10ECh. 14 - How does temperature affect the solubility of a...Ch. 14 - Prob. 12ECh. 14 - How does pressure affect the solubility of a gas...Ch. 14 - What is Henry’s law? For what kinds of...Ch. 14 - Prob. 15ECh. 14 - How are parts by mass and parts by volume used in...Ch. 14 - Prob. 17ECh. 14 - What is Raoult’s law? For what kind of...Ch. 14 - Explain the difference between an ideal and a...Ch. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - What are colligative properties?Ch. 14 - Prob. 23ECh. 14 - Explain the significance of the van’t Hoff factor...Ch. 14 - Prob. 25ECh. 14 - Pick an appropriate solvent from Table 13.3 to...Ch. 14 - Which molecule would you expect to be more soluble...Ch. 14 - Prob. 28ECh. 14 - Prob. 29ECh. 14 - Prob. 30ECh. 14 - When ammonium chloride (NH4Cl) is dissolved in...Ch. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Use the given data to calculate the heats of...Ch. 14 - Lithium iodide has a lattice energy of...Ch. 14 - Prob. 36ECh. 14 - A solution contains 25 g of NaCl per 100.0 g of...Ch. 14 - A solution contains 32 g of KNO3 per 100.0 g of...Ch. 14 - Prob. 39ECh. 14 - A KCI solution containing 42 g of KCI per 100.0 g...Ch. 14 - Some laboratory procedures involving...Ch. 14 - A person preparing a fish tank fills the tank with...Ch. 14 - Prob. 43ECh. 14 - Scuba divers breathing air at increased pressure...Ch. 14 - Calculate the mass of nitrogen dissolved at room...Ch. 14 - Use Henry’s law to determine the molar solubility...Ch. 14 - An aqueous NaCl solution is made using 112 g of...Ch. 14 - Prob. 48ECh. 14 - To what volume should you dilute 50.0 mL of a...Ch. 14 - Prob. 50ECh. 14 - Silver nitrate solutions are used to plate silver...Ch. 14 - Prob. 52ECh. 14 - Prob. 53ECh. 14 - Prob. 54ECh. 14 - You can purchase nitric acid in a concentrated...Ch. 14 - You can purchase hydrochloric acid in a...Ch. 14 - Prob. 57ECh. 14 - Prob. 58ECh. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - A beaker contains 100.0 mL of pure water. A second...Ch. 14 - Which solution has the highest vapor pressure? a....Ch. 14 - Calculate the vapor pressure of a solution...Ch. 14 - A solution contains naphthalene (C10H8) dissolved...Ch. 14 - A solution contains 50.0 g of heptane (C7H16) and...Ch. 14 - A solution contains a mixture of pentane and...Ch. 14 - A solution contains 4.08 g of chloroform (C3H8O3)...Ch. 14 - A solution of methanol and water has a mole...Ch. 14 - Prob. 73ECh. 14 - An ethylene glycol solution contains 21.2 g of...Ch. 14 - Calculate the freezing point and melting point of...Ch. 14 - Calculate the freezing point and melting point of...Ch. 14 - An aqueous solution containing 17.5 g of an...Ch. 14 - An aqueous solution containing 35.9 g of an...Ch. 14 - Calculate the osmotic pressure of a solution...Ch. 14 - Prob. 80ECh. 14 - A solution containing 27.55 mg of an unknown...Ch. 14 - Prob. 82ECh. 14 - Calculate the freezing point and boiling point...Ch. 14 - Calculate the freezing point and boiling point in...Ch. 14 - What mass of salt (NaCl) should you add to 1.00 L...Ch. 14 - Prob. 86ECh. 14 - Use the van’t Hoff factors in Table 13.7 to...Ch. 14 - Prob. 88ECh. 14 - A 1.2-m aqueous solution of an ionic compound with...Ch. 14 - A 0.95-m aqueous solution of an ionic compound...Ch. 14 - Prob. 91ECh. 14 - Prob. 92ECh. 14 - Prob. 93ECh. 14 - An aqueous CaCl2 solution has a vapor pressure of...Ch. 14 - Prob. 95ECh. 14 - Prob. 96ECh. 14 - Potassium perchlorate (KClO4) has a lattice energy...Ch. 14 - Sodium hydroxide (NaOH) has a lattice energy of...Ch. 14 - Prob. 99ECh. 14 - Prob. 100ECh. 14 - Prob. 101ECh. 14 - Water softeners often replace calcium ions in hard...Ch. 14 - Prob. 103ECh. 14 - Prob. 104ECh. 14 - Prob. 105ECh. 14 - Prob. 106ECh. 14 - An isotonic solution contains 0.90% NaCl mass to...Ch. 14 - Prob. 108ECh. 14 - Prob. 109ECh. 14 - When HNO2 dissolves in water, it partially...Ch. 14 - Prob. 111ECh. 14 - Prob. 112ECh. 14 - Prob. 113ECh. 14 - Distillation is a method of purification based on...Ch. 14 - Prob. 115ECh. 14 - Find the mass of urea (CH4N2O) needed to prepare...Ch. 14 - A solution contains 10.05 g of unknown compound...Ch. 14 - Prob. 118ECh. 14 - Prob. 119ECh. 14 - Prob. 120ECh. 14 - The small bubbles that form on the bottom of a...Ch. 14 - The vapor above a mixture of pentane and hexane at...Ch. 14 - A 1.10-g sample contains only glucose (C6H12O6)...Ch. 14 - Prob. 124ECh. 14 - Two alcohols, isopropyl alcohol and propyl...Ch. 14 - A metal, M, of atomic mass 96 amu reacts with...Ch. 14 - Prob. 127ECh. 14 - Prob. 128ECh. 14 - A solution is prepared by dissolving 11.60 g of a...Ch. 14 - Substance A is a nonpolar liquid and has only...Ch. 14 - Prob. 131ECh. 14 - Prob. 132ECh. 14 - Prob. 133ECh. 14 - Prob. 134E
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY