a) Interpretation: To predict the signals of the following molecules in its 1 H and 13 C spectra.

Question

Q1: a) Arrange the compounds in order of decreasing pKa, highest first. ОН ΟΗ ῸΗ дон ОН ОН CI Br

Answer 1

Question

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

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Q1: a) Arrange the compounds in order of decreasing pKa, highest first. ОН ΟΗ ῸΗ дон ОН ОН CI Br

(4 pts - 2 pts each part) A route that can be taken to prepare a hydrophobic (water-repellent) aerogel is to start with trichloromethylsilane, CH3SiCl3 as the silicon source. a. What is the chemical reaction that this undergoes to form a product with Si-OH groups? Write as complete of a chemical equation as you can. CI CI-SI-CH3 CI b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you didn't already answer it in part (a)) and how/why does it form?

b) Circle the substrate that would not efficiently generate a Grignard reagent upon reaction with Mg in ether. CI Br ד c) Circle the Grignard reagents that contain incompatible functional groups. MgBr HO MgBr MgBr MgBr MgBr HO MgBr

Answer 2

Question

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

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Answer 3

Question

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

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Answer 4

Question

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

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Answer 5

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 6

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 7

Chapter 13.SE, Problem 36AP

Interpretation Introduction

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 8

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 9

Interpretation Introduction

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 10

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 11

Interpretation Introduction

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Answer 12

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Answer 13

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Answer 23

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - The following 1H NMR peaks were recorded on a...Ch. 13.3 - When the 1Î— NMR spectrum of acetone, CH3COCH3, is...Ch. 13.4 - Each of the following compounds has a single 1H...Ch. 13.4 - Identify the different types of protons in the...Ch. 13.5 - How many peaks would you expect in the 1H NMR...Ch. 13.6 - Predict the splitting patterns you would expect...Ch. 13.6 - Draw structures for compounds that meet the...

a) Interpretation: To predict the signals of the following molecules in its 1 H and 13 C spectra.

Solution Summary: The author explains the structure of the compound, which has 4 methyl groups and 2 13 C-NMR peaks.

Concept explainers

a)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

b)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

c)

Interpretation:

To predict the signals of the following molecules in its ¹H and ¹³C spectra.

Chapter 13 Solutions

a) Interpretation: To predict the signals of the following molecules in its 1 H and 13 C spectra.

Solution Summary: The author explains the structure of the compound, which has 4 methyl groups and 2 13 C-NMR peaks.

Concept explainers