The products for the following reactions are to be predicted. Concept Introduction: Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond. Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET ) A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst. To predict the product of reaction

Question

Want to see the full answer?

Answer 1

Question

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

Answer 2

Question

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 6

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 7

Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 8

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 9

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 10

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 11

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 12

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 13

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

To predict the product of reaction

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 13.2 - Prob. 1LTS Ch. 13.2 - Prob. 1PTS Ch. 13.2 - Prob. 2PTS Ch. 13.2 - Prob. 3ATS Ch. 13.4 - Prob. 4CC Ch. 13.5 - Prob. 2LTS Ch. 13.5 - PRACTICE the skill Show reagents that you could...Ch. 13.5 - APPLY the skill Compound 2 was made as a...Ch. 13.5 - Prob. 7CC Ch. 13.5 - Prob. 8CC

Want to see the full answer?

Chapter 13 Solutions