ORGANIC CHEMISTRY 1 TERM ACCESS
ORGANIC CHEMISTRY 1 TERM ACCESS
3rd Edition
ISBN: 9781119661511
Author: Klein
Publisher: WILEY
Question
Book Icon
Chapter 13.9, Problem 15CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  1

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  2       ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  3

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  4

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  5

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  6

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  7       ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  8

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  9

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  10

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  11

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  12       ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  13

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  14

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  15

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  16

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  17       ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  18

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  19

ORGANIC CHEMISTRY 1 TERM ACCESS, Chapter 13.9, Problem 15CC , additional homework tip  20

To predict the product of reaction

Blurred answer
Students have asked these similar questions
A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3
1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

Chapter 13 Solutions

ORGANIC CHEMISTRY 1 TERM ACCESS

Ch. 13.5 - Prob. 9CCCh. 13.6 - Prob. 10CCCh. 13.7 - Prob. 11CCCh. 13.7 - Prob. 12CCCh. 13.8 - Prob. 3LTSCh. 13.8 - Prob. 13PTSCh. 13.8 - Prob. 14ATSCh. 13.9 - Prob. 15CCCh. 13.10 - Prob. 4LTSCh. 13.10 - Prob. 16PTSCh. 13.10 - Prob. 17ATSCh. 13.10 - Prob. 5LTSCh. 13.10 - Prob. 18PTSCh. 13.10 - The sequence below shows an enantioselective...Ch. 13.11 - Prob. 20CCCh. 13.11 - Prob. 21CCCh. 13.12 - Prob. 6LTSCh. 13.12 - Prob. 22PTSCh. 13.12 - Prob. 23ATSCh. 13.12 - Prob. 7LTSCh. 13.12 - Prob. 24PTSCh. 13.12 - Prob. 25ATSCh. 13 - Prob. 26PPCh. 13 - Prob. 27PPCh. 13 - Prob. 28PPCh. 13 - Prob. 29PPCh. 13 - Prob. 30PPCh. 13 - Prob. 31PPCh. 13 - Prob. 32PPCh. 13 - Methylmagnesium bromide reacts rapidly with...Ch. 13 - Prob. 34PPCh. 13 - Prob. 35PPCh. 13 - Prob. 36PPCh. 13 - Prob. 37PPCh. 13 - Prob. 38PPCh. 13 - Prob. 39PPCh. 13 - Prob. 40PPCh. 13 - Prob. 41PPCh. 13 - Prob. 42PPCh. 13 - Prob. 43PPCh. 13 - Prob. 44PPCh. 13 - Prob. 45PPCh. 13 - Prob. 46IPCh. 13 - Prob. 47IPCh. 13 - Prob. 48IPCh. 13 - Prob. 49IPCh. 13 - Prob. 50IPCh. 13 - Prob. 51IPCh. 13 - Prob. 52IPCh. 13 - Prob. 53IPCh. 13 - Prob. 54IPCh. 13 - Prob. 55IPCh. 13 - Prob. 56IPCh. 13 - Prob. 57IPCh. 13 - Prob. 58IPCh. 13 - Prob. 59IPCh. 13 - Prob. 60IPCh. 13 - Prob. 61IPCh. 13 - Prob. 62IPCh. 13 - Prob. 63IPCh. 13 - Prob. 64IPCh. 13 - Prob. 65IPCh. 13 - Prob. 66IPCh. 13 - Prob. 67IPCh. 13 - Prob. 68IPCh. 13 - Prob. 69IPCh. 13 - Prob. 70IPCh. 13 - The following procedure13 is part of a synthetic...Ch. 13 - Prob. 72CPCh. 13 - Prob. 73CPCh. 13 - Prob. 74CPCh. 13 - Prob. 75CP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY