Starting material and reagents required to prepare the given epoxide need to be identified. Concept introduction: Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows: Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other. The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water. The reactions involved in the preparation are as follows The above reaction takes place via intramolecular Williamson ether synthesis . This is an S N 2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Question

Want to see the full answer?

Answer 1

Question

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Name the family to which each organic compound belongs. The first answer has been filled in for you. compound CH₂ || CH3-C-NH2 0 ။ CH3-C-CH₂ CH=O–CH=CH, CH₂ HO CH2-CH2-CH-CH3 family amine D

1b. Br LOH

I would like my graphs checked please. Do they look right? Do I have iodine and persulfate on the right axis ?

Answer 2

Question

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Answer 6

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Answer 7

Chapter 13.8, Problem 3LTS

Interpretation Introduction

Interpretation: Starting material and reagents required to prepare the given epoxide need to be identified.

Concept introduction:

Preparation of epoxide- Epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, the general reaction is represented as follows:

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. The formation of epoxide via peroxy acid is a stereospecific process; thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

The preparation of epoxides from halohydrins can simply take place upon treatment with a strong base. Here, halohydrin can be formed from alkene after treatment with a halogen in the presence of water.

The reactions involved in the preparation are as follows

The above reaction takes place via intramolecular Williamson ether synthesis. This is an S_N2-like process where an alkoxide ion acts as a nucleophile. This is also a stereospecific process.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 13.2 - Prob. 1LTS Ch. 13.2 - Prob. 1PTS Ch. 13.2 - Prob. 2PTS Ch. 13.2 - Prob. 3ATS Ch. 13.4 - Prob. 4CC Ch. 13.5 - Prob. 2LTS Ch. 13.5 - Prob. 5PTS Ch. 13.5 - Prob. 6ATS Ch. 13.5 - Prob. 7CC Ch. 13.5 - Prob. 8CC

Solution Summary: The author explains that epoxides can be prepared via two methods, one with peroxy acids and the other with halohydrins.

Concept explainers

Want to see the full answer?

Chapter 13 Solutions