ORGANIC CHEM PRINT STUDY GDE & SSM
ORGANIC CHEM PRINT STUDY GDE & SSM
4th Edition
ISBN: 9781119810650
Author: Klein
Publisher: WILEY
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Chapter 13.8, Problem 13PTS

(a)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  1

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  2

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

(b)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  3

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  4

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

(c)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  5

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  6

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

(d)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  7

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEM PRINT STUDY GDE & SSM, Chapter 13.8, Problem 13PTS , additional homework tip  8

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

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