(a) Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown. Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane. Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base. The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

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Answer 1

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

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Answer 2

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 3

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 4

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 5

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

Answer 6

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Answer 7

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Answer 8

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

Answer 9

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author explains the steps and reagents needed to convert cyclohexane into given compound.

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