ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
Question
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Chapter 13.7, Problem 12CC

a)

Interpretation Introduction

Interpretation: The name of compound should be assigned along with chirality centre and configuration.

Concept Introduction:

The compounds that contain an Oxygen atom incorporated in a ring are called as cyclic ethers. Special parent names are given to represent the ring size.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  1   ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  2   ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  3  ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  4

There are two methods of naming Epoxides.

First method: Oxygen atom is taken as substituent on the parent chain and the precise location of the Epoxide group is identified with two numbers given by the term Epoxy.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  5

Second method: Oxirane is considered as parent ring and those groups that are connected to Oxirane ring are given as substituents.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  6

b)

Interpretation Introduction

Interpretation: The name of compound should be assigned along with chirality centre and configuration.

Concept Introduction:

The compounds that contain an Oxygen atom incorporated in a ring are called as cyclic ethers. Special parent names are given to represent the ring size.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  7   ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  8   ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  9  ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  10

There are two methods of naming Epoxides.

First method: Oxygen atom is taken as substituent on the parent chain and the precise location of the Epoxide group is identified with two numbers given by the term Epoxy.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  11

Second method: Oxirane is considered as parent ring and those groups that are connected to Oxirane ring are given as substituents.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  12

c)

Interpretation Introduction

Interpretation: The name of compound should be assigned along with chirality centre and configuration.

Concept Introduction:

The compounds that contain an Oxygen atom incorporated in a ring are called as cyclic ethers. Special parent names are given to represent the ring size.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  13   ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  14   ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  15  ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  16

There are two methods of naming Epoxides.

First method: Oxygen atom is taken as substituent on the parent chain and the precise location of the Epoxide group is identified with two numbers given by the term Epoxy.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  17

Second method: Oxirane is considered as parent ring and those groups that are connected to Oxirane ring are given as substituents.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 13.7, Problem 12CC , additional homework tip  18

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Chapter 13 Solutions

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY

Ch. 13.5 - Prob. 9CCCh. 13.6 - Prob. 10CCCh. 13.7 - Prob. 11CCCh. 13.7 - Prob. 12CCCh. 13.8 - Prob. 3LTSCh. 13.8 - Prob. 13PTSCh. 13.8 - Prob. 14ATSCh. 13.9 - Prob. 15CCCh. 13.10 - Prob. 4LTSCh. 13.10 - Prob. 16PTSCh. 13.10 - Prob. 17ATSCh. 13.10 - Prob. 5LTSCh. 13.10 - Prob. 18PTSCh. 13.10 - The sequence below shows an enantioselective...Ch. 13.11 - Prob. 20CCCh. 13.11 - Prob. 21CCCh. 13.12 - Prob. 6LTSCh. 13.12 - Prob. 22PTSCh. 13.12 - Prob. 23ATSCh. 13.12 - Prob. 7LTSCh. 13.12 - Prob. 24PTSCh. 13.12 - Prob. 25ATSCh. 13 - Prob. 26PPCh. 13 - Prob. 27PPCh. 13 - Prob. 28PPCh. 13 - Prob. 29PPCh. 13 - Prob. 30PPCh. 13 - Prob. 31PPCh. 13 - Prob. 32PPCh. 13 - Methylmagnesium bromide reacts rapidly with...Ch. 13 - Prob. 34PPCh. 13 - Prob. 35PPCh. 13 - Prob. 36PPCh. 13 - Prob. 37PPCh. 13 - Prob. 38PPCh. 13 - Prob. 39PPCh. 13 - Prob. 40PPCh. 13 - Prob. 41PPCh. 13 - Prob. 42PPCh. 13 - Prob. 43PPCh. 13 - Prob. 44PPCh. 13 - Prob. 45PPCh. 13 - Prob. 46IPCh. 13 - Prob. 47IPCh. 13 - Prob. 48IPCh. 13 - Prob. 49IPCh. 13 - Prob. 50IPCh. 13 - Prob. 51IPCh. 13 - Prob. 52IPCh. 13 - Prob. 53IPCh. 13 - Prob. 54IPCh. 13 - Prob. 55IPCh. 13 - Prob. 56IPCh. 13 - Prob. 57IPCh. 13 - Prob. 58IPCh. 13 - Prob. 59IPCh. 13 - Prob. 60IPCh. 13 - Prob. 61IPCh. 13 - Prob. 62IPCh. 13 - Prob. 63IPCh. 13 - Prob. 64IPCh. 13 - Prob. 65IPCh. 13 - Prob. 66IPCh. 13 - Prob. 67IPCh. 13 - Prob. 68IPCh. 13 - Prob. 69IPCh. 13 - Prob. 70IPCh. 13 - The following procedure13 is part of a synthetic...Ch. 13 - Prob. 72CPCh. 13 - Prob. 73CPCh. 13 - Prob. 74CPCh. 13 - Prob. 75CP
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