(a) Interpretation: The given compound is to be synthesized from ( CH 3 ) 3 CH . Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane.

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Answer 1

Question

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

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#1 (a). Provide the expected product for the following reaction of A to B by indicating what the product is after step 1 (call this "81") and after step 2 (call this product "B2"). Give a complete mechanism for the transformation of compound A into compound B showing all intermediates, resonance structures, stereochemistry and electron movements 1. Et-MgBr 2. Me-Br B #1 (b). Compound A can be prepared in one step from an alkene starting material. Provide the structure a and the reaction conditions required to convert it to compound A The starting alkene

Answer 2

Question

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

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Answer 3

Question

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

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Answer 4

Question

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

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Answer 5

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Answer 6

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 7

Chapter 13.7, Problem 11P

Interpretation Introduction

(a)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given compound is to be synthesized from (CH3)3CH.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author explains that halogens react with alkanes in presence of heat or light to form alkyl

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