Concept explainers
(a)
Interpretation: Nomenclature needs to be done for the given compound.
Concept Introduction: Nomenclature of
First method- Parent
Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.
(b)
Interpretation: Nomenclature needs to be done for the given compound.
Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in a three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and is known as ethylene oxide. Naming is done by two methods.
First method- Parent alkane chain is identified and oxygen is considered as a substituent on that chain. The location of the epoxide group is written with two numbers with the suffix epoxy. While naming, epoxy substituents are alphabetically arranged.
Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.
(c)
Interpretation: Nomenclature needs to be done for the given compound.
Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in a three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and is known as ethylene oxide. Naming is done by two methods.
First method- Parent alkane chain is identified and oxygen is considered as a substituent on that chain. The location of the epoxide group is written with two numbers with the suffix epoxy. While naming, epoxy substituents are alphabetically arranged.
Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.
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Chapter 13 Solutions
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
- 2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forwardE17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.arrow_forward
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