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Concept explainers
(a)
Interpretation:
The reagents used to prepare the given ethers via
Concept introduction:
Williamson Ether Synthesis: Alcohols
The first step in this reaction is forming the conjugate base of the alcohol (called an alkoxide) by the reaction of the alcohol with sodium metal. This reaction forms hydrogen gas
(b)
Interpretation:
The reagents used to prepare the given ethers via Williamson ether synthesis has to be given.
Concept introduction:
Williamson Ether Synthesis: Alcohols
The first step in this reaction is forming the conjugate base of the alcohol (called an alkoxide) by the reaction of the alcohol with sodium metal. This reaction forms hydrogen gas
(c)
Interpretation:
The reagents used to prepare the given ethers via Williamson ether synthesis has to be given.
Concept introduction:
Williamson Ether Synthesis: Alcohols
The first step in this reaction is forming the conjugate base of the alcohol (called an alkoxide) by the reaction of the alcohol with sodium metal. This reaction forms hydrogen gas
(d)
Interpretation:
The reagents used to prepare the given ethers via Williamson ether synthesis has to be given.
Concept introduction:
Williamson Ether Synthesis: Alcohols
The first step in this reaction is forming the conjugate base of the alcohol (called an alkoxide) by the reaction of the alcohol with sodium metal. This reaction forms hydrogen gas
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Chapter 13 Solutions
Organic Chemistry, Third Edition Binder Ready Version
- The highest boiling compound from among the following isA. 2-methylheptane; B. 3-methylheptane; C. 2,2-dimethylhexane;D. octane; E. 2,2,3-trimethylpentanearrow_forwardWhich of the following features are found in the most stable structure ofCH5NO that does not have a CO bond?w. a π bond, x. two NH bonds, y. one OH bond, z. 3 lone pairsA. w, x; B. x, y; C. y, z; D. x, y, z; E. all of them.arrow_forwardWhich one of the following functional groups is not present in thecompound shownA. amine; B. aldehyde, C. ether; D. amide. E. ketonearrow_forward
- Which of the following formulas correspond to at least one compound inwhich resonance is important?w. C2H5N x. C3H5Br; y. C3H4; z. C4H6.A. w, x, y; B. x, y, z; C. w, x, z; D. w, y, z; E. all of themarrow_forwardPredict the product(s) that are formed after each step for reactions 1-4. In each case, consider formation of any chiral center(s) and draw all expected stereoisomers. 1) OH 1) HBr (SN2) 2) NaOH, heat 3) BH3, THF 4) H2O2, NaOH 2) OH 1) SOCI 2, py 2) NaOEt 3) Br2, H₂O 3) OH 1) H2SO4 conc. 2) HBr, ROOR 3) KOtBu 4) OH 1) TsCl, py 2) NaOEt 3) 03 4) DMSarrow_forwardWhich of the following rings has the least strain in its most stableconformation?A. Cyclobutane; B. Cyclopentane; C. Cyclohexane; D. Cycloheptane;E. Cyclooctanearrow_forward
- The number of different carbon skeletons that have a main chain of 9carbons and an ethyl branch isA 3; B. 4; C. 5; D. 6; E. 7arrow_forwardQ5: Classify the following pair of molecules as constitutional isomers, enantiomers, diastereomers, the same molecule, or completely different molecules. Br O CI Br OH OH 111 Br .!!!/Br F OH and ...m Br Br OH CI Br OH ་་་་་" ། ་arrow_forwardConsidering only rotation around the 1-2 bond, how many differentstaggered conformations are there of 1,2-dibromo-1,2-dichloropropane?A: 2; B. 3; C. 4; D. 6; E. more than 6.arrow_forward
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