Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 13.5, Problem 13P

(a)

Interpretation Introduction

Interpretation:

Aldehyde or ketone that is obtained when the given compound is heated in basic aqueous solution to be identified.

Concept introduction:

Aldol reaction is an addition reaction of aldehydes and ketones.

Mechanism for the aldol addition is given as,

Essential Organic Chemistry (3rd Edition), Chapter 13.5, Problem 13P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

Aldehyde or ketone that is obtained when the given compound is heated in basic aqueous solution to be identified.

Concept introduction:

Aldol reaction is an addition reaction of aldehydes and ketones.

Mechanism for the aldol addition:

Essential Organic Chemistry (3rd Edition), Chapter 13.5, Problem 13P , additional homework tip  2

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1
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Essential Organic Chemistry (3rd Edition)

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