Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 13.5, Problem 13P

(a)

Interpretation Introduction

Interpretation:

Aldehyde or ketone that is obtained when the given compound is heated in basic aqueous solution to be identified.

Concept introduction:

Aldol reaction is an addition reaction of aldehydes and ketones.

Mechanism for the aldol addition is given as,

Essential Organic Chemistry (3rd Edition), Chapter 13.5, Problem 13P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

Aldehyde or ketone that is obtained when the given compound is heated in basic aqueous solution to be identified.

Concept introduction:

Aldol reaction is an addition reaction of aldehydes and ketones.

Mechanism for the aldol addition:

Essential Organic Chemistry (3rd Edition), Chapter 13.5, Problem 13P , additional homework tip  2

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

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Essential Organic Chemistry (3rd Edition)

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