GENERAL,ORGANIC,+BIOCHEM.(LL) >CUSTOM<
GENERAL,ORGANIC,+BIOCHEM.(LL) >CUSTOM<
10th Edition
ISBN: 9781264116546
Author: Denniston
Publisher: MCG CUSTOM
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Chapter 13.4, Problem 13.13Q

(a)

Interpretation Introduction

Interpretation:

The structure has to be identified as acetal or hemiacetal.

Concept Introduction:

Hemiacetal is characterized by a carbon, which is bonded to one hydroxyl group (-OH) and one alkoxy group (-OR).

Hemiacetals are unstable.  In the presence of acid and excess alcohol, they undergo a substitution reaction in which the -OH group of the hemiacetal is exchange for another -OR group from the alcohol.  The product formed is called as acetal.  A carbon bonded to two alkoxy groups (-OR) is the called as acetal.

(b)

Interpretation Introduction

Interpretation:

The structure has to be identified as acetal or hemiacetal.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The structure has to be identified as acetal or hemiacetal.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The structure has to be identified as acetal or hemiacetal.

Concept Introduction:

Refer to part (a).

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Chapter 13 Solutions

GENERAL,ORGANIC,+BIOCHEM.(LL) >CUSTOM<

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