CHEMISTRY
13th Edition
ISBN: 9781292228860
Author: Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 13.2, Problem 13.19PP
Identify the chiral carbon in each of the following compounds:
a. citronellol; one enantiomer has the odor of geranium
b. alanine,an amino acid
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and
dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a
resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if
applicable).
ード
M
4-
b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible
isomers and their corresponding point groups. Use the point groups to determine if the complexes have
resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if
applicable). The number of complex sketches below is not necessarily indicative of the number of isomers.
4-
4-
☐☐☐
c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible
isomers and their corresponding point groups.. Use the point groups to determine if the complexes have
resulting net dipole…
Show work. don't give Ai generated solution
Chapter 13 Solutions
CHEMISTRY
Ch. 13.1 - Prob. 13.1PPCh. 13.1 - Prob. 13.2PPCh. 13.1 - Prob. 13.3PPCh. 13.1 - Prob. 13.4PPCh. 13.1 - Prob. 13.5PPCh. 13.1 - Prob. 13.6PPCh. 13.1 - Prob. 13.7PPCh. 13.1 - Prob. 13.8PPCh. 13.1 - Prob. 13.9PPCh. 13.1 - Prob. 13.10PP
Ch. 13.2 - Prob. 13.11PPCh. 13.2 - Prob. 13.12PPCh. 13.2 - Prob. 13.13PPCh. 13.2 - Prob. 13.14PPCh. 13.2 - Prob. 13.15PPCh. 13.2 - Prob. 13.16PPCh. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify the chiral carbon in each of the...Ch. 13.2 - Prob. 13.20PPCh. 13.3 - Prob. 13.21PPCh. 13.3 - Prob. 13.22PPCh. 13.3 - Prob. 13.23PPCh. 13.3 - Prob. 13.24PPCh. 13.3 - Prob. 13.25PPCh. 13.3 - Prob. 13.26PPCh. 13.3 - Prob. 13.27PPCh. 13.3 - Prob. 13.28PPCh. 13.3 - Prob. 13.29PPCh. 13.3 - Prob. 13.30PPCh. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - Prob. 13.33PPCh. 13.4 - Prob. 13.34PPCh. 13.4 - Prob. 13.35PPCh. 13.4 - Identify each of the following as the a or ß...Ch. 13.5 - Prob. 13.37PPCh. 13.5 - Prob. 13.38PPCh. 13.5 - Prob. 13.39PPCh. 13.5 - Prob. 13.40PPCh. 13.6 - Prob. 13.41PPCh. 13.6 - Prob. 13.42PPCh. 13.6 - Prob. 13.43PPCh. 13.6 - Prob. 13.44PPCh. 13.6 - Prob. 13.45PPCh. 13.6 - Prob. 13.46PPCh. 13.7 - Describe the similarities and differences in the...Ch. 13.7 - Prob. 13.48PPCh. 13.7 - Prob. 13.49PPCh. 13.7 - Prob. 13.50PPCh. 13.7 - Prob. 13.51PPCh. 13.7 - Prob. 13.52PPCh. 13.7 - Prob. 13.53PPCh. 13.7 - Prob. 13.54PPCh. 13 - Prob. 13.55UTCCh. 13 - Prob. 13.56UTCCh. 13 - Prob. 13.57UTCCh. 13 - Prob. 13.58UTCCh. 13 - Prob. 13.59UTCCh. 13 - Prob. 13.60UTCCh. 13 - Prob. 13.61APPCh. 13 - Prob. 13.62APPCh. 13 - Prob. 13.63APPCh. 13 - Prob. 13.64APPCh. 13 - Prob. 13.65APPCh. 13 - Prob. 13.66APPCh. 13 - Prob. 13.67APPCh. 13 - Prob. 13.68APPCh. 13 - Prob. 13.69APPCh. 13 - Prob. 13.70APPCh. 13 - Prob. 13.71APPCh. 13 - Prob. 13.72APPCh. 13 - Prob. 13.73APPCh. 13 - Prob. 13.74APPCh. 13 - Prob. 13.75CPCh. 13 - Prob. 13.76CPCh. 13 - 13.77 Gentiobiose is found in saffron. (13.4,...Ch. 13 - Prob. 13.78CP
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