ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
4th Edition
ISBN: 9781119745105
Author: Klein
Publisher: WILEY
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Chapter 13.11, Problem 20CC

(a)

Interpretation Introduction

Interpretation: Starting material and reagent used to prepare the given thiols need to be identified.

  ORGANIC CHEMISTRY, Chapter 13.11, Problem 20CC , additional homework tip  1

Concept introduction: preparation of thiol can be done when alkyl halide reacts with sodium hydrosulfide. The reaction follows the SN2 mechanism. Here, the substitution of the SH group takes place, and halide act as leaving group. Since it is an SN2 reaction, thus, inversion of the configuration takes place.

(b)

Interpretation Introduction

Interpretation: Starting material and reagent used to prepare the given thiols need to be identified.

  ORGANIC CHEMISTRY, Chapter 13.11, Problem 20CC , additional homework tip  2

Concept introduction: preparation of thiol can be done when alkyl halide reacts with sodium hydrosulfide. The reaction follows the SN2 mechanism. Here, the substitution of the SH group takes place, and halide act as leaving group. Since it is an SN2 reaction, thus, inversion of the configuration takes place.

(c)

Interpretation Introduction

Interpretation: Starting material and reagent used to prepare the given thiols need to be identified.

  ORGANIC CHEMISTRY, Chapter 13.11, Problem 20CC , additional homework tip  3

Concept introduction: preparation of thiol can be done when alkyl halide reacts with sodium hydrosulfide. The reaction follows the SN2 mechanism. Here, the substitution of the SH group takes place, and halide act as leaving group. Since it is an SN2 reaction, thus, inversion of the configuration takes place.

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