Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780321809247
Author: Nivaldo J. Tro
Publisher: Prentice Hall
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Chapter 13, Problem 9E
Interpretation Introduction
To explain: The difference between rate law and integrated law for a reaction.
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b)
H3C-
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Using Luther's rule, determine the reference potentials of the
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-0,28
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Chapter 13 Solutions
Chemistry: A Molecular Approach
Ch. 13 - Q1. This graph shows the concentration of the...Ch. 13 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 13 - Q3. This plot shows the rate of the decomposition...Ch. 13 - Prob. 4SAQCh. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQ
Ch. 13 - Q11. The mechanism shown is proposed for the gas...Ch. 13 - Q12. Which statement is true regarding the...Ch. 13 - Q13. These images represent the first-order...Ch. 13 - Prob. 14SAQCh. 13 - Prob. 15SAQCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - 4. Why is the reaction rate for reactants defined...Ch. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - 8. For a reaction with multiple reactants, how is...Ch. 13 - 9. Explain the difference between the rate law for...Ch. 13 - 10. Write integrated rate laws for zero-order,...Ch. 13 - Prob. 11ECh. 13 - 12. How do reaction rates typically depend on...Ch. 13 - Prob. 13ECh. 13 - 14. What is an Arrhenius plot? Explain the...Ch. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - 17. In a reaction mechanism, what is an elementary...Ch. 13 - 18. What are the two requirements for a proposed...Ch. 13 - 19. What is an intermediate within a reaction...Ch. 13 - Prob. 20ECh. 13 - 21. Explain the difference between homogeneous...Ch. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - 25. Consider the reaction:
2 HBr(g) → H2(g) +...Ch. 13 - 26. Consider the reaction:
2 N2O(g) → 2 N2(g) +...Ch. 13 - 27. For the reaction 2 A(g) + B(g) → 3 C(g),
a....Ch. 13 - 28. For the reaction A(g) + B(g) → 2 C(g),
a....Ch. 13 - 29. Consider the reaction:
Cl2(g) + 3 F2(g) → 2...Ch. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - 33. Consider the reaction:
H2(g) + Br2(g) ? 2...Ch. 13 - 34. Consider the reaction:
2 H2O2(aq) ? 2 H2O(l) +...Ch. 13 - Prob. 35ECh. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - 38. This reaction is first order in N2O5:
N2O5(g)...Ch. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - 42. Consider the data showing the initial rate of...Ch. 13 - 45. The tabulated data were collected for this...Ch. 13 - 46. The tabulated data were collected for this...Ch. 13 - 47. Indicate the order of reaction consistent with...Ch. 13 - 48. Indicate the order of reaction consistent with...Ch. 13 - 49. The tabulated data show the concentration of...Ch. 13 - Prob. 48ECh. 13 - 51. The tabulated data show the concentration of...Ch. 13 - 52. The reaction A → products was monitored as a...Ch. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - 57. The half-life for the radioactive decay of...Ch. 13 - 58. The half-life for the radioactive decay of...Ch. 13 - 5957. The diagram shows the energy of a reaction...Ch. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - 65. The data shown here were collected for the...Ch. 13 - Prob. 64ECh. 13 - 67. The tabulated data were collected for the...Ch. 13 - 68. The tabulated data show the rate constant of a...Ch. 13 - 69. A reaction has a rate constant of 0.0117/s at...Ch. 13 - 70. A reaction has a rate constant of 0.000122/s...Ch. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Prob. 73ECh. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - 79. Many heterogeneous catalysts are deposited on...Ch. 13 - 80. Suppose that the reaction A → products is...Ch. 13 - 81. Suppose that a catalyst lowers the activation...Ch. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 85ECh. 13 - Prob. 86ECh. 13 - Prob. 87ECh. 13 - Prob. 88ECh. 13 - 91. Iodine atoms combine to form I2 in liquid...Ch. 13 - 9290. The hydrolysis of sucrose (C12H22O11) into...Ch. 13 - 9391. The reaction AB(aq) ? A(g) + B(g) is second...Ch. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - 97. The desorption (leaving of the surface) of a...Ch. 13 - Prob. 96ECh. 13 - 99. The kinetics of this reaction were studied as...Ch. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - 102100. Consider the two reactions:
a. Why is...Ch. 13 - 103. Anthropologists can estimate the age of a...Ch. 13 - 104. Geologists can estimate the age of rocks by...Ch. 13 - Prob. 103ECh. 13 - 106104. Consider the reaction:
2 NH3(aq) +...Ch. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - Prob. 108ECh. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - 113. In this chapter we have seen a number of...Ch. 13 - 1124. The first-order integrated rate law for the...Ch. 13 - 115. The previous exercise shows how the...Ch. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - 120118. Consider the reaction:
CHCl3(g) + Cl2(g) ?...Ch. 13 - Prob. 119ECh. 13 - Prob. 120E
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- Using Benzene as starting materia Show how each of the Following molecules could Ve synthesked 9. CHI d. 10450 b 0 -50311 ८ City -5034 1-0-650 e NO2arrow_forwardBA HBr of the fol 1)=MgCI 2) H₂O major NaOEt Ts Cl Py (pyridine) 1) 03 2) Me2S 1arrow_forward4. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a) NHBoc ⚫OBn HO. H3C CO2CH3 -OBn H3C H3C. H3C. NHBOC CI CO2CH3arrow_forward
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- CI 1) n-BuLi 2) 1) 03 HH T&Cl 2) H₂O 2arrow_forwardHelp with a!arrow_forwardFor the following compound: HO -H Draw a mechanism for the tautomerization process under BASIC conditions: Mechanism A: H-O: H-OH H-O HH H-OO Mechanism B: H-Q Mechanism C: Θ OH H-O: Mechanism D: H-O H- H-OO C H-OO H- H- H-OO HH OH -H - HON H :OH H-Harrow_forward
- identify the product (or multiple products) for each of the following reactions: CI 1) NaNH2 (excess) ठ Cl 2) H₂O Hz H₂SO₂, H₂O HgSO Lindlar's catalyst 1) n-BuLi 2) 1)9-BBN 2) H₂O, NaOH ? Br H A B C afó gó H OA B O c OD E OF D E F H H Na, NHarrow_forwardIdentify the product (or multiple products) for each of the following reactions: ? or CI CI 1) NaNHz (excess) 2) H₂O OA OB O C OD OE OF H₂SO₂, H₂O Hq50. 1) n-BuLi 2) Br 1) 9-BBN 2) H₂O₂, NaOH A B H H متته D E H H H H C H H F H H H₂ Lindlar's catalyst Na NHarrow_forwardIdentify the product (or multiple products) for each of the following reactions: O A OB Oc OD OE OF CI CI 1) NaNH2 (excess) 2) H₂O H₂ H₂SO2, H₂O HgSO Lindlar's catalyst 1) n-BuLi 2) Br 1)9-BBN 2) H₂O₂, NaOH ? Na, NH3 C H A H H مننه مننه منن مننه H F H H E مند H D H Harrow_forward
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