Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
3rd Edition
ISBN: 9780321806383
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 13, Problem 85E
Interpretation Introduction
To determine: The rate law, the rate constant, and the total pressure.
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Please explain your steps and thought process. Thank you!
Using the general properties of equilibrium constants
At a certain temperature, the equilibrium constant K for the following reaction is 1.3 × 10 4:
Cl2(g) + CHCl3(g) HCl(g) + CC₁(g)
Use this information to complete the following table.
Suppose a 16. L reaction vessel is filled with 1.6 mol of HCI and
1.6 mol of CCl4. What can you say about the composition of the
mixture in the vessel at equilibrium?
There will be very little Cl2 and CHCl3.
☐ x10
There will be very little HCI and CCl4.
Neither of the above is true.
What is the equilibrium constant for the following reaction? Be
sure your answer has the correct number of significant digits.
HCl(g)+CC14(g)
12
Cl2(9)+CHCl3(9)
K = 0 ☐
What is the equilibrium constant for the following reaction? Be
sure your answer has the correct number of significant digits.
2 Cl₂(9)+2CHCl3(9)
2 HCl(9)+2CC₁₁(9)
K =
✓
00.
18
Ar
Chapter 13 Solutions
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
Ch. 13 - Q1. This graph shows the concentration of the...Ch. 13 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 13 - Q3. This plot shows the rate of the decomposition...Ch. 13 - Prob. 4SAQCh. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQ
Ch. 13 - Q11. The mechanism shown is proposed for the gas...Ch. 13 - Q12. Which statement is true regarding the...Ch. 13 - Q13. These images represent the first-order...Ch. 13 - Prob. 14SAQCh. 13 - Prob. 15SAQCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - 4. Why is the reaction rate for reactants defined...Ch. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - 8. For a reaction with multiple reactants, how is...Ch. 13 - 9. Explain the difference between the rate law for...Ch. 13 - 10. Write integrated rate laws for zero-order,...Ch. 13 - Prob. 11ECh. 13 - 12. How do reaction rates typically depend on...Ch. 13 - Prob. 13ECh. 13 - 14. What is an Arrhenius plot? Explain the...Ch. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - 17. In a reaction mechanism, what is an elementary...Ch. 13 - 18. What are the two requirements for a proposed...Ch. 13 - 19. What is an intermediate within a reaction...Ch. 13 - Prob. 20ECh. 13 - 21. Explain the difference between homogeneous...Ch. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - 25. Consider the reaction:
2 HBr(g) → H2(g) +...Ch. 13 - 26. Consider the reaction:
2 N2O(g) → 2 N2(g) +...Ch. 13 - 27. For the reaction 2 A(g) + B(g) → 3 C(g),
a....Ch. 13 - 28. For the reaction A(g) + B(g) → 2 C(g),
a....Ch. 13 - 29. Consider the reaction:
Cl2(g) + 3 F2(g) → 2...Ch. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - 33. Consider the reaction:
H2(g) + Br2(g) ? 2...Ch. 13 - 34. Consider the reaction:
2 H2O2(aq) ? 2 H2O(l) +...Ch. 13 - Prob. 35ECh. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - 38. This reaction is first order in N2O5:
N2O5(g)...Ch. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - 42. Consider the data showing the initial rate of...Ch. 13 - 45. The tabulated data were collected for this...Ch. 13 - 46. The tabulated data were collected for this...Ch. 13 - 47. Indicate the order of reaction consistent with...Ch. 13 - 48. Indicate the order of reaction consistent with...Ch. 13 - 49. The tabulated data show the concentration of...Ch. 13 - Prob. 48ECh. 13 - 51. The tabulated data show the concentration of...Ch. 13 - 52. The reaction A → products was monitored as a...Ch. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - 57. The half-life for the radioactive decay of...Ch. 13 - 58. The half-life for the radioactive decay of...Ch. 13 - 5957. The diagram shows the energy of a reaction...Ch. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - 65. The data shown here were collected for the...Ch. 13 - Prob. 64ECh. 13 - 67. The tabulated data were collected for the...Ch. 13 - 68. The tabulated data show the rate constant of a...Ch. 13 - 69. A reaction has a rate constant of 0.0117/s at...Ch. 13 - 70. A reaction has a rate constant of 0.000122/s...Ch. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Prob. 73ECh. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - 79. Many heterogeneous catalysts are deposited on...Ch. 13 - 80. Suppose that the reaction A → products is...Ch. 13 - 81. Suppose that a catalyst lowers the activation...Ch. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 85ECh. 13 - Prob. 86ECh. 13 - Prob. 87ECh. 13 - Prob. 88ECh. 13 - 91. Iodine atoms combine to form I2 in liquid...Ch. 13 - 9290. The hydrolysis of sucrose (C12H22O11) into...Ch. 13 - 9391. The reaction AB(aq) ? A(g) + B(g) is second...Ch. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - 97. The desorption (leaving of the surface) of a...Ch. 13 - Prob. 96ECh. 13 - 99. The kinetics of this reaction were studied as...Ch. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - 102100. Consider the two reactions:
a. Why is...Ch. 13 - 103. Anthropologists can estimate the age of a...Ch. 13 - 104. Geologists can estimate the age of rocks by...Ch. 13 - Prob. 103ECh. 13 - 106104. Consider the reaction:
2 NH3(aq) +...Ch. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - Prob. 108ECh. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - 113. In this chapter we have seen a number of...Ch. 13 - 1124. The first-order integrated rate law for the...Ch. 13 - 115. The previous exercise shows how the...Ch. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - 120118. Consider the reaction:
CHCl3(g) + Cl2(g) ?...Ch. 13 - Prob. 119ECh. 13 - Prob. 120E
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