
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
3rd Edition
ISBN: 9780321806383
Author: Nivaldo J. Tro
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 13, Problem 1E
Interpretation Introduction
To explain: Why lizards become sluggish in cold water.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 13 Solutions
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
Ch. 13 - Q1. This graph shows the concentration of the...Ch. 13 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 13 - Q3. This plot shows the rate of the decomposition...Ch. 13 - Prob. 4SAQCh. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQ
Ch. 13 - Q11. The mechanism shown is proposed for the gas...Ch. 13 - Q12. Which statement is true regarding the...Ch. 13 - Q13. These images represent the first-order...Ch. 13 - Prob. 14SAQCh. 13 - Prob. 15SAQCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - 4. Why is the reaction rate for reactants defined...Ch. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - 8. For a reaction with multiple reactants, how is...Ch. 13 - 9. Explain the difference between the rate law for...Ch. 13 - 10. Write integrated rate laws for zero-order,...Ch. 13 - Prob. 11ECh. 13 - 12. How do reaction rates typically depend on...Ch. 13 - Prob. 13ECh. 13 - 14. What is an Arrhenius plot? Explain the...Ch. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - 17. In a reaction mechanism, what is an elementary...Ch. 13 - 18. What are the two requirements for a proposed...Ch. 13 - 19. What is an intermediate within a reaction...Ch. 13 - Prob. 20ECh. 13 - 21. Explain the difference between homogeneous...Ch. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - 25. Consider the reaction:
2 HBr(g) → H2(g) +...Ch. 13 - 26. Consider the reaction:
2 N2O(g) → 2 N2(g) +...Ch. 13 - 27. For the reaction 2 A(g) + B(g) → 3 C(g),
a....Ch. 13 - 28. For the reaction A(g) + B(g) → 2 C(g),
a....Ch. 13 - 29. Consider the reaction:
Cl2(g) + 3 F2(g) → 2...Ch. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - 33. Consider the reaction:
H2(g) + Br2(g) ? 2...Ch. 13 - 34. Consider the reaction:
2 H2O2(aq) ? 2 H2O(l) +...Ch. 13 - Prob. 35ECh. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - 38. This reaction is first order in N2O5:
N2O5(g)...Ch. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - 42. Consider the data showing the initial rate of...Ch. 13 - 45. The tabulated data were collected for this...Ch. 13 - 46. The tabulated data were collected for this...Ch. 13 - 47. Indicate the order of reaction consistent with...Ch. 13 - 48. Indicate the order of reaction consistent with...Ch. 13 - 49. The tabulated data show the concentration of...Ch. 13 - Prob. 48ECh. 13 - 51. The tabulated data show the concentration of...Ch. 13 - 52. The reaction A → products was monitored as a...Ch. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - 57. The half-life for the radioactive decay of...Ch. 13 - 58. The half-life for the radioactive decay of...Ch. 13 - 5957. The diagram shows the energy of a reaction...Ch. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - 65. The data shown here were collected for the...Ch. 13 - Prob. 64ECh. 13 - 67. The tabulated data were collected for the...Ch. 13 - 68. The tabulated data show the rate constant of a...Ch. 13 - 69. A reaction has a rate constant of 0.0117/s at...Ch. 13 - 70. A reaction has a rate constant of 0.000122/s...Ch. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Prob. 73ECh. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - 79. Many heterogeneous catalysts are deposited on...Ch. 13 - 80. Suppose that the reaction A → products is...Ch. 13 - 81. Suppose that a catalyst lowers the activation...Ch. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 85ECh. 13 - Prob. 86ECh. 13 - Prob. 87ECh. 13 - Prob. 88ECh. 13 - 91. Iodine atoms combine to form I2 in liquid...Ch. 13 - 9290. The hydrolysis of sucrose (C12H22O11) into...Ch. 13 - 9391. The reaction AB(aq) ? A(g) + B(g) is second...Ch. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - 97. The desorption (leaving of the surface) of a...Ch. 13 - Prob. 96ECh. 13 - 99. The kinetics of this reaction were studied as...Ch. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - 102100. Consider the two reactions:
a. Why is...Ch. 13 - 103. Anthropologists can estimate the age of a...Ch. 13 - 104. Geologists can estimate the age of rocks by...Ch. 13 - Prob. 103ECh. 13 - 106104. Consider the reaction:
2 NH3(aq) +...Ch. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - Prob. 108ECh. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - 113. In this chapter we have seen a number of...Ch. 13 - 1124. The first-order integrated rate law for the...Ch. 13 - 115. The previous exercise shows how the...Ch. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - 120118. Consider the reaction:
CHCl3(g) + Cl2(g) ?...Ch. 13 - Prob. 119ECh. 13 - Prob. 120E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- О δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα नarrow_forward1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]arrow_forwardhumbnai Concentration Terms[1].pdf ox + New Home Edit Sign in Comment Convert Page Fill & Sign Protect Tools Batch +WPS A Free Trial Share Inter Concreting Concentration forms. Hydrogen peroxide is a powerful oxidizing agent wed in concentrated solution in rocket fuels and in dilute solution as a hair bleach. An aqueous sulation of H2O2 is 30% by mass and has density of #liligime calculat the Ⓒmolality ⑥mole fraction of molarity. 20 9. B. A sample of Commercial Concentrated hydrochloric ETarrow_forward
- If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardWould the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward(a) Sketch the 'H NMR of the following chemical including the approximate chemical shifts, the multiplicity (splitting) of all signals and the integration (b) How many signals would you expect in the 13C NMR? CH3arrow_forward
- Draw the Show the major and minor product(s) for the following reaction mechanisms for both reactions and show all resonance structures for any Explain why the major product is favoured? intermediates H-Brarrow_forwardChoose the right answerarrow_forward8. What is the major product of the following reaction? KMnO4 b a TOH OH OH C d OH "OH HO OH OHarrow_forward
- Choose the right answerarrow_forward3. Draw ALL THE POSSBILE PRODUCTS AND THE MECHANISMS WITH ALL RESONANCE STRUCTURES. Explain using the resonance structures why the major product(s) are formed over the minor product(s). H₂SO4, HONO CHarrow_forward7. Provide the product(s), starting material(s) and/or condition(s) required for the No mechanisms required. below reaction HO + H-I CI FO Br2, FeBr3 O I-Oarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY