Introduction to Chemistry
4th Edition
ISBN: 9781259288722
Author: BAUER
Publisher: MCG
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Chapter 13, Problem 6PP
Interpretation Introduction
Interpretation:
Amongst the given solutions, the solution with greater
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Nucleophilic Aromatic Substitution
22.30 Predict all possible products formed from the following nucleophilic substitution
reactions.
(a)
(b)
9
1. NaOH
2. HCI, H₂O
CI
NH₁(!)
+NaNH,
-33°C
1. NaOH
2. HCl, H₂O
Syntheses
22.35 Show how to convert toluene to these compounds.
(a)
-CH,Br (b) Br-
-CH3
22.36 Show how to prepare each compound from 1-phenyl-1-propanone.
1-Phenyl-1-propanone
ہتی.
Br.
(b)
Br
(racemic)
22.37 Show how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and
(b) 2,4-dichlorobenzoic acid.
22.38 Show reagents and conditions to bring about the following conversions.
(a)
9
NH2
8
CO₂H
NH2
CO₂Et
(d)
NO2
NH2
S
NH₂
NO2
CHS
CH
ive the major organic product(s) of each of the following reactions or sequences of reactions. Show all
rant stereochemistry. [10 only]
A.
B.
NaN3
1. LiAlH4, ether
Br
2. H₂O
CH3
HNO3
H₂/Pt
H₂SO ethanol
C.
0
0
CH3CC1
NaOH
NHCCH
AICI
H₂O
.
NH₂
CH3CH2 N CH2CH3 + HCI
CH₂CH 3
1. LIAIH, THE
2. H₂O
Chapter 13 Solutions
Introduction to Chemistry
Ch. 13 - How do acids and bases differ from other...Ch. 13 - Prob. 2QCCh. 13 - Prob. 3QCCh. 13 - Prob. 4QCCh. 13 - Prob. 5QCCh. 13 - Prob. 6QCCh. 13 - Prob. 1PPCh. 13 - Prob. 2PPCh. 13 - Prob. 3PPCh. 13 - Prob. 4PP
Ch. 13 - Prob. 5PPCh. 13 - Prob. 6PPCh. 13 - Prob. 7PPCh. 13 - Prob. 8PPCh. 13 - Prob. 9PPCh. 13 - Prob. 10PPCh. 13 - Prob. 11PPCh. 13 - Prob. 12PPCh. 13 - Prob. 13PPCh. 13 - Prob. 14PPCh. 13 - Prob. 15PPCh. 13 - Prob. 1QPCh. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - Prob. 6QPCh. 13 - Prob. 7QPCh. 13 - Prob. 8QPCh. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - Prob. 21QPCh. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - Prob. 24QPCh. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - How do strong acids and bases differ from weak...Ch. 13 - Prob. 28QPCh. 13 - Prob. 29QPCh. 13 - Prob. 30QPCh. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - Prob. 33QPCh. 13 - Prob. 34QPCh. 13 - Prob. 35QPCh. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Sodium fluoride, NaF, and sodium acetate,...Ch. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - Prob. 46QPCh. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - Prob. 54QPCh. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - Prob. 57QPCh. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - Prob. 64QPCh. 13 - Prob. 65QPCh. 13 - What is the pH range for acidic solutions? For...Ch. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - Prob. 69QPCh. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Prob. 74QPCh. 13 - Prob. 75QPCh. 13 - Prob. 76QPCh. 13 - Prob. 77QPCh. 13 - Prob. 78QPCh. 13 - Prob. 79QPCh. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - Prob. 84QPCh. 13 - Prob. 85QPCh. 13 - Prob. 86QPCh. 13 - Prob. 87QPCh. 13 - Prob. 88QPCh. 13 - Prob. 89QPCh. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95QPCh. 13 - Prob. 96QPCh. 13 - Prob. 97QPCh. 13 - Prob. 98QPCh. 13 - Prob. 99QPCh. 13 - Prob. 100QPCh. 13 - Prob. 101QPCh. 13 - What would you expect to observe if you ran a...Ch. 13 - Prob. 103QPCh. 13 - Prob. 104QPCh. 13 - Prob. 105QPCh. 13 - Prob. 106QPCh. 13 - Prob. 107QPCh. 13 - Prob. 108QPCh. 13 - Prob. 109QPCh. 13 - Prob. 110QPCh. 13 - Prob. 111QPCh. 13 - Prob. 112QPCh. 13 - Prob. 113QPCh. 13 - Prob. 114QPCh. 13 - Prob. 115QPCh. 13 - Prob. 116QPCh. 13 - Prob. 117QPCh. 13 - Prob. 118QPCh. 13 - Prob. 119QPCh. 13 - Prob. 120QPCh. 13 - Prob. 121QPCh. 13 - Prob. 122QPCh. 13 - Prob. 123QPCh. 13 - Prob. 124QPCh. 13 - Prob. 125QPCh. 13 - Prob. 126QPCh. 13 - Prob. 127QPCh. 13 - Prob. 128QPCh. 13 - Prob. 129QPCh. 13 - What is the pH of a mixture that contains...Ch. 13 - Prob. 131QPCh. 13 - Prob. 132QPCh. 13 - Prob. 133QPCh. 13 - Which of the following weak acids has the anion...Ch. 13 - Prob. 135QPCh. 13 - Prob. 136QPCh. 13 - Prob. 137QPCh. 13 - Prob. 138QPCh. 13 - Prob. 139QPCh. 13 - Prob. 140QPCh. 13 - Prob. 141QPCh. 13 - Prob. 142QPCh. 13 - Prob. 143QPCh. 13 - Prob. 144QPCh. 13 - Prob. 145QPCh. 13 - Prob. 146QPCh. 13 - When 10.0mLofa0.10MHCl solution is diluted to...Ch. 13 - Consider a buffer solution prepared by adding...
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- Calculate the stoichiometric amount of CaCl2 needed to convert all of the CuSO4 into CuCl2.arrow_forwardH CH تنی Cl 1. NaCN, DMF 2. LIAIH4, ether H₂O pyridine N NH₂ 5 CH H 1 HNO, H₂SO 2. Nal NH2 Br Br HNO₂ CuCl H₂SO HCI CH3 H3C NN HSO KCN CuCN 1. HNO₂, H₂SO O₂N NH2 2. OH ཀ་ལས། །ས་ཅན་ :i་དེ་མ་མ་སེ་ NH₂ CH3 1. HNO₂, H₂SO4 2. H3PO₂ 1 HNO2, H2SO4 2. Nalarrow_forwardive the major organic product(s) of each of the following reactions or sequences of reactions. Show all rant stereochemistry. [10 only] A. B. NaN3 1. LiAlH4, ether Br 2. H₂O CH3 HNO3 H₂/Pt H₂SO ethanol C. 0 0 CH3CC1 NaOH NHCCH AICI H₂O . NH₂ CH3CH2 N CH2CH3 + HCI CH₂CH 3 1. LIAIH, THE 2. H₂Oarrow_forward
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- . Choose a structure from the list provided below that best fits each of the following escriptions. Place the letter of the structure in the blank to the left of the description. There is nly one correct answer for each question. starch HO CH₂OH b. cellulose d. CH₂OH HO OH HO HO OH OH OH f. sucrose CH₂OH OH OH HO OCH₂ OH a monosaccharide that gives a negative Benedict's Test. a ẞ-1,4'-glycoside a disaccharidearrow_forwardShow how each of the following transformations might be best accomplished. More than one step may required. Show all reagents and all intermediate structures. [4 only] CH3 A. CH CH2 C Br CH3 CH3 CH3CH2 C NH2 CH3 B OH any source of carbon N MIHarrow_forwardConsider the reaction below to answer the following questions. 0 0 25 PS ES 1919sds-III msx H H + 5% NaOCH 3, CH3OHA O CH₂OH Jeiniog 2E1 gniwool of mor]. Ignibuloni 9vil 19 A B 11 >buoqm gniwollol so dass 101 tomboy boo-11Coble or to r ton auch i viw ninlaxs, noitsausbroo 152 lobla ogsbau ton 250b br A. Which carbonyl compound functions as the electrophile in this reaction? B. Draw the structure of the enolate ion that is generated during the course of this reaction. C. This reaction is an example of: a. a mixed Claisen condensation. b. C. d. a Dieckman condensation. a Michael reaction. a mixed aldol reaction. HD HDarrow_forward
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