Introduction to Chemistry
4th Edition
ISBN: 9780073523002
Author: Rich Bauer, James Birk Professor Dr., Pamela S. Marks
Publisher: McGraw-Hill Education
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Chapter 13, Problem 6PP
Interpretation Introduction
Interpretation:
Amongst the given solutions, the solution with greater
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Nucleophilic Aromatic Substitution
22.30 Predict all possible products formed from the following nucleophilic substitution
reactions.
(a)
(b)
9
1. NaOH
2. HCI, H₂O
CI
NH₁(!)
+NaNH,
-33°C
1. NaOH
2. HCl, H₂O
Syntheses
22.35 Show how to convert toluene to these compounds.
(a)
-CH,Br (b) Br-
-CH3
22.36 Show how to prepare each compound from 1-phenyl-1-propanone.
1-Phenyl-1-propanone
ہتی.
Br.
(b)
Br
(racemic)
22.37 Show how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and
(b) 2,4-dichlorobenzoic acid.
22.38 Show reagents and conditions to bring about the following conversions.
(a)
9
NH2
8
CO₂H
NH2
CO₂Et
(d)
NO2
NH2
S
NH₂
NO2
CHS
CH
ive the major organic product(s) of each of the following reactions or sequences of reactions. Show all
rant stereochemistry. [10 only]
A.
B.
NaN3
1. LiAlH4, ether
Br
2. H₂O
CH3
HNO3
H₂/Pt
H₂SO ethanol
C.
0
0
CH3CC1
NaOH
NHCCH
AICI
H₂O
.
NH₂
CH3CH2 N CH2CH3 + HCI
CH₂CH 3
1. LIAIH, THE
2. H₂O
Chapter 13 Solutions
Introduction to Chemistry
Ch. 13 - How do acids and bases differ from other...Ch. 13 - Prob. 2QCCh. 13 - Prob. 3QCCh. 13 - Prob. 4QCCh. 13 - Prob. 5QCCh. 13 - Prob. 6QCCh. 13 - Prob. 1PPCh. 13 - Prob. 2PPCh. 13 - Prob. 3PPCh. 13 - Prob. 4PP
Ch. 13 - Prob. 5PPCh. 13 - Prob. 6PPCh. 13 - Prob. 7PPCh. 13 - Prob. 8PPCh. 13 - Prob. 9PPCh. 13 - Prob. 10PPCh. 13 - Prob. 11PPCh. 13 - Prob. 12PPCh. 13 - Prob. 13PPCh. 13 - Prob. 14PPCh. 13 - Prob. 15PPCh. 13 - Prob. 1QPCh. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - Prob. 6QPCh. 13 - Prob. 7QPCh. 13 - Prob. 8QPCh. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - Prob. 21QPCh. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - Prob. 24QPCh. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - How do strong acids and bases differ from weak...Ch. 13 - Prob. 28QPCh. 13 - Prob. 29QPCh. 13 - Prob. 30QPCh. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - Prob. 33QPCh. 13 - Prob. 34QPCh. 13 - Prob. 35QPCh. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Sodium fluoride, NaF, and sodium acetate,...Ch. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - Prob. 46QPCh. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - Prob. 54QPCh. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - Prob. 57QPCh. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - Prob. 64QPCh. 13 - Prob. 65QPCh. 13 - What is the pH range for acidic solutions? For...Ch. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - Prob. 69QPCh. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Prob. 74QPCh. 13 - Prob. 75QPCh. 13 - Prob. 76QPCh. 13 - Prob. 77QPCh. 13 - Prob. 78QPCh. 13 - Prob. 79QPCh. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - Prob. 84QPCh. 13 - Prob. 85QPCh. 13 - Prob. 86QPCh. 13 - Prob. 87QPCh. 13 - Prob. 88QPCh. 13 - Prob. 89QPCh. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95QPCh. 13 - Prob. 96QPCh. 13 - Prob. 97QPCh. 13 - Prob. 98QPCh. 13 - Prob. 99QPCh. 13 - Prob. 100QPCh. 13 - Prob. 101QPCh. 13 - What would you expect to observe if you ran a...Ch. 13 - Prob. 103QPCh. 13 - Prob. 104QPCh. 13 - Prob. 105QPCh. 13 - Prob. 106QPCh. 13 - Prob. 107QPCh. 13 - Prob. 108QPCh. 13 - Prob. 109QPCh. 13 - Prob. 110QPCh. 13 - Prob. 111QPCh. 13 - Prob. 112QPCh. 13 - Prob. 113QPCh. 13 - Prob. 114QPCh. 13 - Prob. 115QPCh. 13 - Prob. 116QPCh. 13 - Prob. 117QPCh. 13 - Prob. 118QPCh. 13 - Prob. 119QPCh. 13 - Prob. 120QPCh. 13 - Prob. 121QPCh. 13 - Prob. 122QPCh. 13 - Prob. 123QPCh. 13 - Prob. 124QPCh. 13 - Prob. 125QPCh. 13 - Prob. 126QPCh. 13 - Prob. 127QPCh. 13 - Prob. 128QPCh. 13 - Prob. 129QPCh. 13 - What is the pH of a mixture that contains...Ch. 13 - Prob. 131QPCh. 13 - Prob. 132QPCh. 13 - Prob. 133QPCh. 13 - Which of the following weak acids has the anion...Ch. 13 - Prob. 135QPCh. 13 - Prob. 136QPCh. 13 - Prob. 137QPCh. 13 - Prob. 138QPCh. 13 - Prob. 139QPCh. 13 - Prob. 140QPCh. 13 - Prob. 141QPCh. 13 - Prob. 142QPCh. 13 - Prob. 143QPCh. 13 - Prob. 144QPCh. 13 - Prob. 145QPCh. 13 - Prob. 146QPCh. 13 - When 10.0mLofa0.10MHCl solution is diluted to...Ch. 13 - Consider a buffer solution prepared by adding...
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- Calculate the stoichiometric amount of CaCl2 needed to convert all of the CuSO4 into CuCl2.arrow_forwardH CH تنی Cl 1. NaCN, DMF 2. LIAIH4, ether H₂O pyridine N NH₂ 5 CH H 1 HNO, H₂SO 2. Nal NH2 Br Br HNO₂ CuCl H₂SO HCI CH3 H3C NN HSO KCN CuCN 1. HNO₂, H₂SO O₂N NH2 2. OH ཀ་ལས། །ས་ཅན་ :i་དེ་མ་མ་སེ་ NH₂ CH3 1. HNO₂, H₂SO4 2. H3PO₂ 1 HNO2, H2SO4 2. Nalarrow_forwardive the major organic product(s) of each of the following reactions or sequences of reactions. Show all rant stereochemistry. [10 only] A. B. NaN3 1. LiAlH4, ether Br 2. H₂O CH3 HNO3 H₂/Pt H₂SO ethanol C. 0 0 CH3CC1 NaOH NHCCH AICI H₂O . NH₂ CH3CH2 N CH2CH3 + HCI CH₂CH 3 1. LIAIH, THE 2. H₂Oarrow_forward
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