(a) Interpretation: The difference between central atom and terminal atom is to be stated. Concept introduction: Molecular geometry is the 3 − D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Question

The data for the potential difference of a battery and its temperature are given in the table. Calculate the entropy change in J mol-1 K-1 (indicate the formulas used).Data: F = 96485 C mol-1

Answer 1

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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The data for the potential difference of a battery and its temperature are given in the table. Calculate the entropy change in J mol-1 K-1 (indicate the formulas used).Data: F = 96485 C mol-1

In a cell, the change in entropy (AS) can be calculated from the slope of the E° vs 1/T graph. The slope is equal to -AS/R, where R is the gas constant. Is this correct?

Using the Arrhenius equation, it is possible to establish the relationship between the rate constant (k) of a chemical reaction and the temperature (T), in Kelvin (K), the universal gas constant (R), the pre-exponential factor (A) and the activation energy (Ea). This equation is widely applied in studies of chemical kinetics, and is also widely used to determine the activation energy of reactions. In this context, the following graph shows the variation of the rate constant with the inverse of the absolute temperature, for a given chemical reaction that obeys the Arrhenius equation. Based on the analysis of this graph and the concepts acquired about the kinetics of chemical reactions, analyze the following statements: I. The activation energy (Ea) varies with the temperature of the system. II. The activation energy (Ea) varies with the concentration of the reactants. III. The rate constant (K) varies proportionally with temperature. IV. The value of the…

Answer 2

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 3

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 4

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 5

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 6

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 7

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 18

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Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 2E Ch. 13 - Prob. 3E Ch. 13 - Prob. 4E Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 6E Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 8E Ch. 13 - Prob. 9E Ch. 13 - Prob. 10E

Chapter 13 Solutions