CHEMISTRY+CHEM...HYBRID ED.(LL)>CUSTOM<
9th Edition
ISBN: 9781305020788
Author: John C.Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: CENGAGE C
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Chapter 13, Problem 64GQ
The solubility of NaCl in water at 100 °C is 39.1 g/100. g of water Calculate the boiling point of this solution. (Assume i = 1.85 for NaCl.)
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 13 Solutions
CHEMISTRY+CHEM...HYBRID ED.(LL)>CUSTOM<
Ch. 13.1 - (a) If you dissolve 10.0 g (about one heaping...Ch. 13.1 - You dissolve 1.0 mol of urea (H2NCONH2) in 270 g...Ch. 13.1 - 2. The concentration of acetic acid, CH3CO2H, in a...Ch. 13.2 - Use the data in Table 13.1 to calculate the...Ch. 13.2 - Given the enthalpy of formation data below,...Ch. 13.3 - Prob. 1CYUCh. 13.3 - Prob. 1RCCh. 13.3 - If the headspace of a soda is 25 mL and the...Ch. 13.3 - Prob. 2QCh. 13.3 - Prob. 3Q
Ch. 13.3 - Prob. 4QCh. 13.4 - Assume you dissolve 10.0 g of sucrose (C12H22O11)...Ch. 13.4 - What quantity of ethylene glycol, HOCH2CH2OH, must...Ch. 13.4 - In the northern United States, summer cottages are...Ch. 13.4 - Bradykinin is a small peptide (9 amino acids; 1060...Ch. 13.4 - An aluminum-containing compound has the empirical...Ch. 13.4 - A 1.40-g sample of polyethylene, a common plastic,...Ch. 13.4 - Calculate the freezing point of 525 g of water...Ch. 13.4 - 1. Vapor pressure: Arrange the following aqueous...Ch. 13.4 - Prob. 2RCCh. 13.4 - Samples of each of the substances listed below are...Ch. 13.4 - Motor mass: Erythritol is a compound that occurs...Ch. 13.5 - Prob. 1RCCh. 13.5 - The blue line on the diagram illustrates the...Ch. 13.5 - How many theoretical plates are required to...Ch. 13.5 - Prob. 3QCh. 13.5 - The vapor pressure of pure heptane is 361.5 mm Hg...Ch. 13 - You dissolve 2.56 g of succinic acid, C2H4(CO2H)2,...Ch. 13 - You dissolve 45.0 g of camphor, C10H16O, in 425 mL...Ch. 13 - Prob. 3PSCh. 13 - Prob. 4PSCh. 13 - Prob. 5PSCh. 13 - Prob. 6PSCh. 13 - Prob. 7PSCh. 13 - Prob. 8PSCh. 13 - Hydrochloric acid is sold as a concentrated...Ch. 13 - Concentrated sulfuric acid has a density of 1.84...Ch. 13 - The average lithium ion concentration in seawater...Ch. 13 - Silver ion has an average concentration of 28 ppb...Ch. 13 - Which pairs of liquids will be miscible? (a) H2O...Ch. 13 - Acetone, CH3COCH3, is quite soluble in water....Ch. 13 - Prob. 15PSCh. 13 - Use the following data to calculate the enthalpy...Ch. 13 - You make a saturated solution of NaCl at 25 C. No...Ch. 13 - Some lithium chloride, LiCl, is dissolved in 100...Ch. 13 - Prob. 19PSCh. 13 - The Henrys law constant for O2 in water at 25 is...Ch. 13 - An unopened soda can has an aqueous CO2...Ch. 13 - Hydrogen gas has a Henrys law constant of 7.8 104...Ch. 13 - A sealed flask contains water and oxygen gas at 25...Ch. 13 - Butane, C4H10, has been suggested as the...Ch. 13 - A 35.0-g sample of ethylene glycol, HOCH2CH2OH, is...Ch. 13 - Urea, (NH2)2CO, which is widely used in...Ch. 13 - Pure ethylene glycol, HOCH2CH2OH, is added 2.00 kg...Ch. 13 - Pure iodine (105 g) is dissolved in 325 g of CCl4...Ch. 13 - Prob. 29PSCh. 13 - What is the boiling point of a solution composed...Ch. 13 - Prob. 31PSCh. 13 - Prob. 32PSCh. 13 - Prob. 33PSCh. 13 - Some ethylene glycol, HOCH2CH2OH, is added to your...Ch. 13 - You dissolve 15.0 g of sucrose, C12H22O11, in a...Ch. 13 - A typical bottle of wine consists of an 11%...Ch. 13 - Prob. 37PSCh. 13 - Estimate the osmotic pressure of human blood at 37...Ch. 13 - An aqueous solution containing 1.00 g of bovine...Ch. 13 - Calculate the osmotic pressure of a 0.0120 M...Ch. 13 - You add 0.255 g of an orange, crystalline compound...Ch. 13 - Butylated hydroxyanisole (BHA) is used in...Ch. 13 - Benzyl acetate is one of the active components of...Ch. 13 - Anthracene, a hydrocarbon obtained from coal, has...Ch. 13 - An aqueous solution contains 0.180 g of an...Ch. 13 - Aluminon, an organic compound, is used as a...Ch. 13 - Prob. 47PSCh. 13 - To make homemade ice cream, you cool the milk and...Ch. 13 - List the following aqueous solutions in order of...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - When solutions of BaCl2 and Na2SO4 are mixed, the...Ch. 13 - The dispersed phase of a certain colloidal...Ch. 13 - Phenylcarbinol is used in nasal sprays as a...Ch. 13 - (a) Which aqueous solution is expected to have the...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - Prob. 56GQCh. 13 - Dimethylglyoxime [DMG, (CH3CNOH)2] is used as a...Ch. 13 - A 10.7 m solution of NaOH has a density of 1.33...Ch. 13 - Concentrated aqueous ammonia has a molarity of...Ch. 13 - Prob. 60GQCh. 13 - If you want a solution that is 0.100 m in ions,...Ch. 13 - Consider the following aqueous solutions: (i) 0.20...Ch. 13 - (a) Which solution is expected to have the higher...Ch. 13 - The solubility of NaCl in water at 100 C is 39.1...Ch. 13 - Instead of using NaCl to melt the ice on your...Ch. 13 - The smell of ripe raspberries is due to...Ch. 13 - Hexachlorophene has been used in germicidal soap....Ch. 13 - The solubility of ammonium formate, NH4CHO2, in...Ch. 13 - How much N2 can dissolve in water at 25 C if the...Ch. 13 - Cigars are best stored in a humidor at 18 C and...Ch. 13 - An aqueous solution containing 10.0 g of starch...Ch. 13 - Prob. 72GQCh. 13 - Calculate the enthalpies of solution for Li2SO4...Ch. 13 - Water at 25 C has a density of 0.997 g/cm3....Ch. 13 - If a volatile solute is added to a volatile...Ch. 13 - A solution is made by adding 50.0 mL of ethanol...Ch. 13 - A 2.0% (by mass) aqueous solution of novocainium...Ch. 13 - A solution is 4.00% (by mass) maltose and 96.00%...Ch. 13 - The following table lists the concentrations of...Ch. 13 - A tree is 10.0 m tall. (a) What must be the total...Ch. 13 - Prob. 81GQCh. 13 - A compound is known to be a potassium halide, KX....Ch. 13 - Prob. 85GQCh. 13 - If one is very careful, it is possible to float a...Ch. 13 - A solution of benzoic acid in benzene has a...Ch. 13 - You dissolve 5.0 mg of iodine, I2, in 25 mL of...Ch. 13 - Prob. 89ILCh. 13 - In a police forensics lab, you examine a package...Ch. 13 - An organic compound contains carbon (71.17%),...Ch. 13 - Prob. 92ILCh. 13 - When sails of Mg2+, Ca2+, and Be2+ are placed in...Ch. 13 - Explain why a cucumber shrivels up when it is...Ch. 13 - Prob. 95SCQCh. 13 - A 100.-gram sample of sodium chloride (NaCl) is...Ch. 13 - Prob. 97SCQCh. 13 - Prob. 98SCQCh. 13 - Starch contains CC, CH, CO, and OH bonds....Ch. 13 - Prob. 100SCQCh. 13 - You have two aqueous solutions separated by a...Ch. 13 - Prob. 102SCQCh. 13 - Sodium chloride (NaCl) is commonly used to melt...Ch. 13 - Prob. 105SCQCh. 13 - Prob. 106SCQCh. 13 - Prob. 107SCQ
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY