ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Question
Chapter 13, Problem 62IP
Interpretation Introduction
Interpretation:
The given
Concept introduction:
Pinacol rearrangement: It is an acid catalyst rearrangement, when 1,2-
Oxidation is the loss of electrons or an increase in oxidation state by a molecule, atom, or ion.
Reduction is the gain of electrons or a decrease in oxidation state by a molecule, atom, or ion.
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2CIO2 + 20H-1 CIO31 + CIO2 + H2O
Experiment
[CIO2], M
[OH-1], M
1
0.0500
0.100
23
2
0.100
0.100
3
0.100
0.0500
Initial Rate, M/s
0.0575
0.230
0.115
...
Given this date, calculate the overall order of this reaction.
2
3
.(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I
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[1-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
0.000069
4
0.0025
0.0025
0.000140
Calculate the rate constant of this reaction using the table data.
1
2
3
4
I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq)
Experiment
[I-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
Calculate the overall order of this reaction using the table data.
0.0025
0.000069
0.0025
0.000140
Chapter 13 Solutions
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
Ch. 13.1 - Prob. 1LTSCh. 13.1 - Prob. 1PTSCh. 13.1 - Prob. 2ATSCh. 13.1 - Prob. 3CCCh. 13.2 - Prob. 4CCCh. 13.2 - Prob. 2LTSCh. 13.2 - Prob. 5PTSCh. 13.2 - Prob. 6ATSCh. 13.3 - Prob. 7CCCh. 13.3 - Prob. 8CC
Ch. 13.4 - Prob. 3LTSCh. 13.4 - Prob. 9PTSCh. 13.4 - Prob. 10ATSCh. 13.4 - Prob. 11ATSCh. 13.4 - Prob. 4LTSCh. 13.4 - Prob. 12PTSCh. 13.4 - Prob. 13ATSCh. 13.6 - Prob. 5LTSCh. 13.6 - Prob. 14PTSCh. 13.6 - Prob. 15ATSCh. 13.6 - Prob. 16ATSCh. 13.6 - Prob. 17ATSCh. 13.7 - Prob. 18CCCh. 13.9 - Prob. 6LTSCh. 13.9 - Prob. 19PTSCh. 13.9 - Prob. 20ATSCh. 13.9 - Prob. 21CCCh. 13.10 - Prob. 7LTSCh. 13.10 - Prob. 22PTSCh. 13.10 - Prob. 23ATSCh. 13.13 - Prob. 8LTSCh. 13.13 - Prob. 24PTSCh. 13.13 - Prob. 25ATSCh. 13.13 - Prob. 26ATSCh. 13.13 - Prob. 27CCCh. 13.13 - Prob. 9LTSCh. 13.13 - Prob. 28PTSCh. 13.13 - Prob. 29ATSCh. 13 - Prob. 30PPCh. 13 - Prob. 31PPCh. 13 - Prob. 32PPCh. 13 - Prob. 33PPCh. 13 - Prob. 34PPCh. 13 - Prob. 35PPCh. 13 - Prob. 36PPCh. 13 - Prob. 37PPCh. 13 - Prob. 38PPCh. 13 - Prob. 39PPCh. 13 - Prob. 40PPCh. 13 - Prob. 41PPCh. 13 - Prob. 42PPCh. 13 - Prob. 43PPCh. 13 - Prob. 44PPCh. 13 - Prob. 45PPCh. 13 - Prob. 46PPCh. 13 - Prob. 47PPCh. 13 - Prob. 48PPCh. 13 - Prob. 49PPCh. 13 - Prob. 50PPCh. 13 - Prob. 51IPCh. 13 - Prob. 52IPCh. 13 - Prob. 53IPCh. 13 - Prob. 54IPCh. 13 - Prob. 55IPCh. 13 - Prob. 56IPCh. 13 - Prob. 57IPCh. 13 - Prob. 58IPCh. 13 - Prob. 59IPCh. 13 - Prob. 60IPCh. 13 - Prob. 61IPCh. 13 - Prob. 62IPCh. 13 - Prob. 63IP
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