(a) Interpretation: The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk. Concept Introduction : A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

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Answer 1

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Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

Answer 2

Question

Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

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Answer 3

Question

Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

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Answer 4

Question

Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

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Answer 5

Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

Answer 6

Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Answer 7

Chapter 13, Problem 5Q

Interpretation Introduction

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13 - Prob. 3Q Ch. 13 - Prob. 4Q Ch. 13 - Prob. 5Q Ch. 13 - Prob. 6Q Ch. 13 - Prob. 7Q Ch. 13 - Prob. 8Q Ch. 13 - Prob. 9Q

(a) Interpretation: The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk. Concept Introduction : A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Solution Summary: The author explains that Caryophyllene is a bicyclic molecule with two stereocenters, and eugenol is not chiral.

Concept explainers

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

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Chapter 13 Solutions

(a) Interpretation: The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk. Concept Introduction : A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

Solution Summary: The author explains that Caryophyllene is a bicyclic molecule with two stereocenters, and eugenol is not chiral.

Concept explainers

(a) Interpretation: The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk. Concept Introduction: A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

(b) Interpretation: Whether eugenol is chiral or not needs to be explained. Concept Introduction: A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.

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Chapter 13 Solutions

(a)

Interpretation:

The structure of Caryophyllene must be drawn and the stereocenters must be marked with asterisk.

Concept Introduction:

A stereocenter contains four differentgroups in which interchange of two groups leads to new stereoisomer.

(b)

Interpretation:

Whether eugenol is chiral or not needs to be explained.

Concept Introduction:

A chiral molecule must have asymmetric environment lacking plane of symmetry, centre of symmetry or rotation reflex ion axis of symmetry.