INTRODUCTORY CHEMISTRY
9th Edition
ISBN: 9780357858998
Author: ZUMDAHL
Publisher: CENGAGE C
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Chapter 13, Problem 59QAP
What pressure exists in a
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
0.2 mol of KOH is added to
1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
0.10 mol of HI is added to
1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
other: ☐
0,0,...
ด
?
18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
무ㅎ
?
Chapter 13 Solutions
INTRODUCTORY CHEMISTRY
Ch. 13.1 - Prob. 13.1SCCh. 13.2 - Prob. 13.2SCCh. 13.3 - Prob. 1CTCh. 13.3 - trong>Exercise 13.3 A child blows a bubble that...Ch. 13.4 - Prob. 13.4SCCh. 13.5 - trong>Exercise 13.5 A weather balloon contains...Ch. 13.5 - Prob. 13.6SCCh. 13.5 - Prob. 13.7SCCh. 13.5 - trong>Exercise 13.8 A sample of argon gas with a...Ch. 13.6 - Prob. 13.9SC
Ch. 13.6 - Prob. 13.10SCCh. 13.8 - Prob. 1CTCh. 13.10 - trong>Exercise 13.11 Calculate the volume of...Ch. 13.10 - at if STP was defined as normal room temperature...Ch. 13.10 - Prob. 13.12SCCh. 13 - Prob. 1ALQCh. 13 - Prob. 2ALQCh. 13 - Prob. 3ALQCh. 13 - Prob. 4ALQCh. 13 - Prob. 5ALQCh. 13 - Prob. 6ALQCh. 13 - Prob. 7ALQCh. 13 - Prob. 8ALQCh. 13 - Prob. 9ALQCh. 13 - Prob. 10ALQCh. 13 - Prob. 11ALQCh. 13 - Prob. 12ALQCh. 13 - Prob. 13ALQCh. 13 - Draw molecular—level views than show the...Ch. 13 - Prob. 15ALQCh. 13 - Prob. 16ALQCh. 13 - Prob. 17ALQCh. 13 - Prob. 18ALQCh. 13 - Prob. 19ALQCh. 13 - Prob. 20ALQCh. 13 - You are holding two balloons of the same volume....Ch. 13 - Prob. 22ALQCh. 13 - Prob. 23ALQCh. 13 - The introduction to this chapter says that "we...Ch. 13 - Prob. 2QAPCh. 13 - Prob. 3QAPCh. 13 - Prob. 4QAPCh. 13 - Prob. 5QAPCh. 13 - Prob. 6QAPCh. 13 - Prob. 7QAPCh. 13 - Prob. 8QAPCh. 13 - Prob. 9QAPCh. 13 - Prob. 10QAPCh. 13 - Make the indicated pressure conversions....Ch. 13 - Prob. 12QAPCh. 13 - Prob. 13QAPCh. 13 - Prob. 14QAPCh. 13 - Prob. 15QAPCh. 13 - Prob. 16QAPCh. 13 - Prob. 17QAPCh. 13 - Prob. 18QAPCh. 13 - Prob. 19QAPCh. 13 - Prob. 20QAPCh. 13 - Prob. 21QAPCh. 13 - Prob. 22QAPCh. 13 - 3. A sample of helium gas with a volume of...Ch. 13 - Prob. 24QAPCh. 13 - Prob. 25QAPCh. 13 - Prob. 26QAPCh. 13 - Prob. 27QAPCh. 13 - Prob. 28QAPCh. 13 - A sample of gas in a balloon has an initial...Ch. 13 - Suppose a 375mLsample of neon gas at 78Cis cooled...Ch. 13 - For each of the following sets of...Ch. 13 - For each of the following sets of...Ch. 13 - Prob. 33QAPCh. 13 - Prob. 34QAPCh. 13 - Suppose 1.25Lof argon is cooled from 291Kto 78K....Ch. 13 - Suppose a 125mLsample of argon is cooled from...Ch. 13 - Prob. 37QAPCh. 13 - Prob. 38QAPCh. 13 - Prob. 39QAPCh. 13 - Prob. 40QAPCh. 13 - Prob. 41QAPCh. 13 - If :math>1.04gof chlorine gas occupies a volume of...Ch. 13 - If 3.25moles of argon gas occupies a volume of...Ch. 13 - Prob. 44QAPCh. 13 - Prob. 45QAPCh. 13 - Prob. 46QAPCh. 13 - Prob. 47QAPCh. 13 - Prob. 48QAPCh. 13 - Prob. 49QAPCh. 13 - Prob. 50QAPCh. 13 - Prob. 51QAPCh. 13 - Determine the pressure in a 125Ltank containing...Ch. 13 - Prob. 53QAPCh. 13 - Prob. 54QAPCh. 13 - Prob. 55QAPCh. 13 - Suppose that a 1.25gsample of neon gas is confined...Ch. 13 - At what temperature will a 1.0gsample of neon gas...Ch. 13 - Prob. 58QAPCh. 13 - What pressure exists in a 200Ltank containing...Ch. 13 - Prob. 60QAPCh. 13 - Suppose a 24.3mLsample of helium gas at 25Cand...Ch. 13 - Prob. 62QAPCh. 13 - Prob. 63QAPCh. 13 - Prob. 64QAPCh. 13 - Prob. 65QAPCh. 13 - Prob. 66QAPCh. 13 - Prob. 67QAPCh. 13 - Suppose than 1.28gof neon gas and 2.49gof argon...Ch. 13 - A tank contains a mixture of 52.5gof oxygen gas...Ch. 13 - What mass of new gas would but required to fill a...Ch. 13 - Prob. 71QAPCh. 13 - Prob. 72QAPCh. 13 - A 500mLsample of O2gas at 24Cwas prepared by...Ch. 13 - Prob. 74QAPCh. 13 - Prob. 75QAPCh. 13 - Prob. 76QAPCh. 13 - Prob. 77QAPCh. 13 - Prob. 78QAPCh. 13 - Prob. 79QAPCh. 13 - Prob. 80QAPCh. 13 - Prob. 81QAPCh. 13 - Prob. 82QAPCh. 13 - Prob. 83QAPCh. 13 - Prob. 84QAPCh. 13 - Calcium oxide can be used to “scrub" carbon...Ch. 13 - Consider the following reaction:...Ch. 13 - Consider the following reaction for the combustion...Ch. 13 - Although we: generally think of combustion...Ch. 13 - m>89. Ammonia and gaseous hydrogen chloride...Ch. 13 - Calcium carbide, CaC2, reacts with water to...Ch. 13 - Prob. 91QAPCh. 13 - Prob. 92QAPCh. 13 - What volume does a mixture of 14.2gof He and...Ch. 13 - Prob. 94QAPCh. 13 - Prob. 95QAPCh. 13 - Consider the following chemical equation:...Ch. 13 - Prob. 97QAPCh. 13 - Dinitrogen monoxide, N2O, reacts with propane,...Ch. 13 - Consider the following unbalanced chemical...Ch. 13 - Prob. 100QAPCh. 13 - Prob. 101QAPCh. 13 - Prob. 102QAPCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - onsider the flasks in the following diagrams. mg...Ch. 13 - Prob. 107APCh. 13 - helium tank contains 25.2Lof helium m 8.40atm...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Prob. 116APCh. 13 - Prob. 117APCh. 13 - 2.50Lcontainer at 1.00atm and 48Cis filled with...Ch. 13 - Prob. 119APCh. 13 - Prob. 120APCh. 13 - Prob. 121APCh. 13 - Prob. 122APCh. 13 - Prob. 123APCh. 13 - f a gaseous mixture is made of 3.50gof He and...Ch. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - f 5.l2gof oxygen gas occupies a volume of 6.21Lat...Ch. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Prob. 132APCh. 13 - t what temperature does 4.00gof helium gas have a...Ch. 13 - Prob. 134APCh. 13 - f 3.20gof nitrogen gas occupies a volume of...Ch. 13 - Prob. 136APCh. 13 - mixture at 33Ccontains H2at 325torr, N2at 475torr,...Ch. 13 - Prob. 138APCh. 13 - Prob. 139APCh. 13 - he following demonstration takes place in a...Ch. 13 - onsider the following unbalanced chemical...Ch. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - Prob. 146APCh. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - omplete the following table for an ideal gas. mg...Ch. 13 - Prob. 151CPCh. 13 - Prob. 152CPCh. 13 - certain flexible weather balloon contains helium...Ch. 13 - Prob. 154CPCh. 13 - Prob. 155CPCh. 13 - Prob. 156CPCh. 13 - Prob. 157CP
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- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. 2.2 mol of NaOH is added to 1.0 L of a 1.4M HF solution. acids: П bases: Х other: ☐ ப acids: 0.51 mol of KOH is added to 1.0 L of a solution that is bases: 1.3M in both HF and NaF. other: ☐ 00. 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: N2O4 (g) 2NO2 (g) AG⁰ = 5.4 kJ Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2O4 tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. yes no 0.42 atm ☑ 5 0/5 ? مله Ararrow_forwardHomework 13 (Ch17) Question 4 of 4 (1 point) | Question Attempt: 2 of 2 ✓ 1 ✓ 2 = 3 4 Time Remaining: 4:25:54 Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction free energy of the following chemical reaction: 2CH3OH (g)+302 (g) → 2CO2 (g) + 4H₂O (g) Round your answer to zero decimal places. ☐ kJ x10 ☐ Subm Check 2020 Hill LLC. All Rights Reserved. Terms of Use | Privacy Cearrow_forward
- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
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