Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134112831
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 13, Problem 49E
Interpretation Introduction
To determine: The mass of nitrogen gas at room temperature.
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34. Give the expected major product of each of the following reactions.
Conc. HI
a. CH3CH2CH2OH
b. (CH3)2CHCH2CH2OH
Conc. HBr
H
Conc. HI
C.
OH
Conc.HCI
d. (CH3CH2)3COH
42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for
alcohol synthesis by subsequent reaction with an aldehyde or ketone? Which ones cannot and why?
H3C CH3
a.
Br
H OH
b.
Cl
C.
I H
H
d. Cl
e.
H
OCH3
Br
H
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
Will the first
MgBr
product that forms in this reaction
create a new CC bond?
olo
?
OH
جمله
O Yes
Ⓒ No
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Click and drag to start drawing a
structure.
Yes
No
X
☐ :
☐
टे
PH
Chapter 13 Solutions
Chemistry: A Molecular Approach (4th Edition)
Ch. 13 - Prob. 1SAQCh. 13 - Prob. 2SAQCh. 13 - Prob. 3SAQCh. 13 - Q4. A potassium bromide solution is 7.55 %...Ch. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQ
Ch. 13 - Prob. 11SAQCh. 13 - Prob. 12SAQCh. 13 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 13 - Q14. A solution is an equimolar mixture of two...Ch. 13 - Prob. 15SAQCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - 22. Explain why the lower vapor pressure for a...Ch. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 13 - 31. Which molecule would you expect to be more...Ch. 13 - 32. Which molecule would you expect to be more...Ch. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 13 - 36. When lithium iodide (LiI) is dissolved in...Ch. 13 - 37. Silver nitrate has a lattice energy of –820...Ch. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - 55. Silver nitrate solutions are often used to...Ch. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - 71. Calculate the vapor pressure of a solution...Ch. 13 - Prob. 72ECh. 13 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 13 - Prob. 74ECh. 13 - 75. A solution contains 4.08 g of chloroform...Ch. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - 80. Calculate the freezing point and boiling point...Ch. 13 - 81. An aqueous solution containing 17.5 g of an...Ch. 13 - Prob. 82ECh. 13 - 83. Calculate the osmotic pressure of a solution...Ch. 13 - Prob. 84ECh. 13 - 85. A solution containing 27.55 mg of an unknown...Ch. 13 - Prob. 86ECh. 13 - 87. Calculate the freezing point and boiling point...Ch. 13 - Prob. 88ECh. 13 - 89. What mass of salt (NaCl) should you add to...Ch. 13 - Prob. 90ECh. 13 - Prob. 91ECh. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - 95. A 0.100 M ionic solution has an osmotic...Ch. 13 - Prob. 96ECh. 13 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - 100. The solubility of phenol in water at 25 °C is...Ch. 13 - Prob. 101ECh. 13 - Prob. 102ECh. 13 - Prob. 103ECh. 13 - Prob. 104ECh. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - 108. The vapor above an aqueous solution contains...Ch. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - Prob. 111ECh. 13 - Prob. 112ECh. 13 - Prob. 113ECh. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - Prob. 118ECh. 13 - Prob. 119ECh. 13 - Prob. 120ECh. 13 - Prob. 121ECh. 13 - Prob. 122ECh. 13 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 13 - Prob. 124ECh. 13 - Prob. 125ECh. 13 - Prob. 126ECh. 13 - 127. A 1.10-g sample contains only glucose...Ch. 13 - 128. A solution is prepared by mixing 631 mL of...Ch. 13 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 13 - Prob. 130ECh. 13 - Prob. 131ECh. 13 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 13 - Prob. 133ECh. 13 - Prob. 134ECh. 13 - Prob. 135ECh. 13 - Prob. 136ECh. 13 - 137. If each substance listed here costs the same...Ch. 13 - Prob. 138ECh. 13 - Prob. 139QGWCh. 13 - Prob. 140QGWCh. 13 - Prob. 141QGWCh. 13 - Prob. 142QGWCh. 13 - Prob. 143QGWCh. 13 - Prob. 144DIA
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- Assign all the carbonsarrow_forward9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00arrow_forwardAssign all the carbonsarrow_forward
- C 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00arrow_forwardCurved arrows were used to generate the significant resonance structure and labeled the most significant contribute. What are the errors in these resonance mechanisms. Draw out the correct resonance mechanisms with an brief explanation.arrow_forwardWhat are the: нсе * Moles of Hice while given: a) 10.0 ml 2.7M ? 6) 10.ome 12M ?arrow_forward
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