Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134112831
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 13, Problem 139QGW
Interpretation Introduction
To explain: The miscibility of
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The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 13 Solutions
Chemistry: A Molecular Approach (4th Edition)
Ch. 13 - Prob. 1SAQCh. 13 - Prob. 2SAQCh. 13 - Prob. 3SAQCh. 13 - Q4. A potassium bromide solution is 7.55 %...Ch. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQ
Ch. 13 - Prob. 11SAQCh. 13 - Prob. 12SAQCh. 13 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 13 - Q14. A solution is an equimolar mixture of two...Ch. 13 - Prob. 15SAQCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - 22. Explain why the lower vapor pressure for a...Ch. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 13 - 31. Which molecule would you expect to be more...Ch. 13 - 32. Which molecule would you expect to be more...Ch. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 13 - 36. When lithium iodide (LiI) is dissolved in...Ch. 13 - 37. Silver nitrate has a lattice energy of –820...Ch. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - 55. Silver nitrate solutions are often used to...Ch. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - 71. Calculate the vapor pressure of a solution...Ch. 13 - Prob. 72ECh. 13 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 13 - Prob. 74ECh. 13 - 75. A solution contains 4.08 g of chloroform...Ch. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - 80. Calculate the freezing point and boiling point...Ch. 13 - 81. An aqueous solution containing 17.5 g of an...Ch. 13 - Prob. 82ECh. 13 - 83. Calculate the osmotic pressure of a solution...Ch. 13 - Prob. 84ECh. 13 - 85. A solution containing 27.55 mg of an unknown...Ch. 13 - Prob. 86ECh. 13 - 87. Calculate the freezing point and boiling point...Ch. 13 - Prob. 88ECh. 13 - 89. What mass of salt (NaCl) should you add to...Ch. 13 - Prob. 90ECh. 13 - Prob. 91ECh. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - 95. A 0.100 M ionic solution has an osmotic...Ch. 13 - Prob. 96ECh. 13 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - 100. The solubility of phenol in water at 25 °C is...Ch. 13 - Prob. 101ECh. 13 - Prob. 102ECh. 13 - Prob. 103ECh. 13 - Prob. 104ECh. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - 108. The vapor above an aqueous solution contains...Ch. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - Prob. 111ECh. 13 - Prob. 112ECh. 13 - Prob. 113ECh. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - Prob. 118ECh. 13 - Prob. 119ECh. 13 - Prob. 120ECh. 13 - Prob. 121ECh. 13 - Prob. 122ECh. 13 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 13 - Prob. 124ECh. 13 - Prob. 125ECh. 13 - Prob. 126ECh. 13 - 127. A 1.10-g sample contains only glucose...Ch. 13 - 128. A solution is prepared by mixing 631 mL of...Ch. 13 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 13 - Prob. 130ECh. 13 - Prob. 131ECh. 13 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 13 - Prob. 133ECh. 13 - Prob. 134ECh. 13 - Prob. 135ECh. 13 - Prob. 136ECh. 13 - 137. If each substance listed here costs the same...Ch. 13 - Prob. 138ECh. 13 - Prob. 139QGWCh. 13 - Prob. 140QGWCh. 13 - Prob. 141QGWCh. 13 - Prob. 142QGWCh. 13 - Prob. 143QGWCh. 13 - Prob. 144DIA
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- a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forwardWhen N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forward
- Consider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forwardNH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.arrow_forwardGiven the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 lowarrow_forward
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- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
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