EBK ESSENTIAL ORGANIC CHEMISTRY
EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 9780100659469
Author: Bruice
Publisher: YUZU
Question
Book Icon
Chapter 13, Problem 42P
Interpretation Introduction

Interpretation:

Product formed when a 1,6-diester instead of a 1,7-diester is used has to be given.

Concept Introduction:

Claisen Condensation is the reaction of an ester having an α hydrogen with one equivalent of a base to yield a β keto ester.

Mechanism for Claisen Condensation:

EBK ESSENTIAL ORGANIC CHEMISTRY, Chapter 13, Problem 42P

  • A base abstracts a proton from the αcarbon forms enolate ion.
  • The enolate ion gets attached to the carbonyl carbon of another ester.
  • The negative charge on oxygen of the carbonyl group reforms, by removing an alkoxide ion.

Blurred answer
Students have asked these similar questions
1. Determine the relationship between the following molecules as identical, diastereomers, or enantiomers (6 points, 2 points each). OH OH OH A-A OH HOT HO- ACHN and HO- ACHN OH HO HO ° OH and OH OH SH and ...SH
20,0 Complete the electron pushing mechanism to y drawing the necomery unicaciones and carved on for Step 1: Add curved arms for the tint step, traiment with NalilĻ. The Nation 458 Step 2: Added for the second step, inalment with), how the "counterion bar Step 3: Daw the products of the last simplom organic and one incoganic spacient, including all nonbonding
please provide the structure for this problem, thank you!
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning