ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter 13, Problem 2LGP
Interpretation Introduction

Interpretation:

The conversion of 2methyl2butene into 2methyl1,3butadiene and ethylbenzene into 3phenylacrylonitrile and the product of the Diels Alder reaction is to be determined.

Concept introduction:

▸ The reagent NBS is used for the allylic bromination of the alkene and the mechanism of the reaction involves the formation of free radicals.

▸ The dehydrohalogenation of halo alkene takes place in the presence of a base like KOH to form the alkene as a product.

▸ The process in which the alkene is treated with ammonia and oxygen for the formation of nitrile is known as Ammoxidation.

▸ A reaction in which dienes and dienophiles react with each other to form the cyclic compound is known as Diels Alder reaction.

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424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)
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Chapter 13 Solutions

ORGANIC CHEM. VOL.1+2-W/WILEYPLUS

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