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Chapter 13, Problem 29E

(a)

Interpretation Introduction

To determine: The appropriate solvents for motor oil.

(b)

Interpretation Introduction

To determine: The appropriate solvents for ethanol.

(c)

Interpretation Introduction

To determine: The appropriate solvents for lard.

(d)

Interpretation Introduction

To determine: The appropriate solvents for potassium chloride.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

Chapter 13 Solutions

Chemistry: A Molecular Approach; Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition (4th Edition)

Ch. 13 - Prob. 11SAQCh. 13 - Prob. 12SAQCh. 13 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 13 - Q14. A solution is an equimolar mixture of two...Ch. 13 - Prob. 15SAQCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - 22. Explain why the lower vapor pressure for a...Ch. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 13 - 31. Which molecule would you expect to be more...Ch. 13 - 32. Which molecule would you expect to be more...Ch. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 13 - 36. When lithium iodide (LiI) is dissolved in...Ch. 13 - 37. Silver nitrate has a lattice energy of –820...Ch. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - 55. Silver nitrate solutions are often used to...Ch. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - 71. Calculate the vapor pressure of a solution...Ch. 13 - Prob. 72ECh. 13 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 13 - Prob. 74ECh. 13 - 75. A solution contains 4.08 g of chloroform...Ch. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - 80. Calculate the freezing point and boiling point...Ch. 13 - 81. An aqueous solution containing 17.5 g of an...Ch. 13 - Prob. 82ECh. 13 - 83. Calculate the osmotic pressure of a solution...Ch. 13 - Prob. 84ECh. 13 - 85. A solution containing 27.55 mg of an unknown...Ch. 13 - Prob. 86ECh. 13 - 87. Calculate the freezing point and boiling point...Ch. 13 - Prob. 88ECh. 13 - 89. What mass of salt (NaCl) should you add to...Ch. 13 - Prob. 90ECh. 13 - Prob. 91ECh. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - 95. A 0.100 M ionic solution has an osmotic...Ch. 13 - Prob. 96ECh. 13 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - 100. The solubility of phenol in water at 25 °C is...Ch. 13 - Prob. 101ECh. 13 - Prob. 102ECh. 13 - Prob. 103ECh. 13 - Prob. 104ECh. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - 108. The vapor above an aqueous solution contains...Ch. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - Prob. 111ECh. 13 - Prob. 112ECh. 13 - Prob. 113ECh. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - Prob. 118ECh. 13 - Prob. 119ECh. 13 - Prob. 120ECh. 13 - Prob. 121ECh. 13 - Prob. 122ECh. 13 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 13 - Prob. 124ECh. 13 - Prob. 125ECh. 13 - Prob. 126ECh. 13 - 127. A 1.10-g sample contains only glucose...Ch. 13 - 128. A solution is prepared by mixing 631 mL of...Ch. 13 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 13 - Prob. 130ECh. 13 - Prob. 131ECh. 13 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 13 - Prob. 133ECh. 13 - Prob. 134ECh. 13 - Prob. 135ECh. 13 - Prob. 136ECh. 13 - 137. If each substance listed here costs the same...Ch. 13 - Prob. 138ECh. 13 - Prob. 139QGWCh. 13 - Prob. 140QGWCh. 13 - Prob. 141QGWCh. 13 - Prob. 142QGWCh. 13 - Prob. 143QGWCh. 13 - Prob. 144DIA
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